TY - JOUR
T1 - Completely fused diporphyrins and tripophyrin
AU - Tsuda, Akihiko
AU - Furuta, Hiroyuki
AU - Osuka, Atsuhiro
PY - 2000/7/17
Y1 - 2000/7/17
N2 - Extremely delocalized π-electronic systems are found in triply linked, fused porphyrins, which are formed by the oxidation of diporphyrins [Eq. (1)]. Stronger electronic interaction is observed in the triply linked diporphyrins, as evidenced by intensified and red-shifted Q bands and by lower one-electron oxidation potentials, as a consequence of their greater planarity. Hence they should have applications as electronic wires.
AB - Extremely delocalized π-electronic systems are found in triply linked, fused porphyrins, which are formed by the oxidation of diporphyrins [Eq. (1)]. Stronger electronic interaction is observed in the triply linked diporphyrins, as evidenced by intensified and red-shifted Q bands and by lower one-electron oxidation potentials, as a consequence of their greater planarity. Hence they should have applications as electronic wires.
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U2 - 10.1002/1521-3773(20000717)39:14<2549::AID-ANIE2549>3.0.CO;2-A
DO - 10.1002/1521-3773(20000717)39:14<2549::AID-ANIE2549>3.0.CO;2-A
M3 - Article
AN - SCOPUS:0034679490
SN - 1433-7851
VL - 39
SP - 2549
EP - 2552
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 14
ER -