Coating of 2D flexible metalorganic frameworks on metal nanocrystals

Naoki Ogiwara, Hirokazu Kobayashi, Keigo Kobayashi, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Hiroshi Kitagawa

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)


We report, for the first time, metal (Pd) nanocrystals (NCs) covered with a 2D flexible metalorganic framework (MOF) of [Zn(NO2-ip)(bpy)]n (NO2-ip: 5-nitro-isophthalate, bpy: 4,4¤-bipyridine). The hybrid materials were characterized by powder X-ray diffraction measurements and transmission electron microscope techniques. The CO2 sorption and hydrogen storage properties revealed that both the flexible porous character of the MOF and the hydrogen absorption ability of Pd NCs were compatible in the hybrid.

Original languageEnglish
Pages (from-to)173-176
Number of pages4
JournalChemistry Letters
Issue number2
Publication statusPublished - 2019

All Science Journal Classification (ASJC) codes

  • General Chemistry


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