TY - JOUR
T1 - Chloride flux growth of La2Ti2O7 crystals and subsequent nitridation to form LaTiO2N crystals
AU - Wagata, Hajime
AU - Zettsu, Nobuyuki
AU - Yamaguchi, Akiko
AU - Nishikiori, Hiromasa
AU - Yubuta, Kunio
AU - Oishi, Shuji
AU - Teshima, Katsuya
N1 - Publisher Copyright:
© 2014 American Chemical Society.
PY - 2015/1/7
Y1 - 2015/1/7
N2 - Highly crystalline, platelike La2Ti2O7 were grown from a NaCl flux, and LaTiO2N crystals were obtained by subsequent nitridation under NH3 flow. The TEM analysis indicated that the flux-grown platelike La2Ti2O7 crystals are single-crystalline growing along the a axis. The shapes and sizes of the LaTiO2N crystals were almost unchanged from the La2Ti2O7 precursor. In addition, LaTiO2N crystals remained single-crystalline with a porous nanostructure. The optical absorption edges of the La2Ti2O7 and LaTiO2N crystals were approximately 320 and 600 nm.
AB - Highly crystalline, platelike La2Ti2O7 were grown from a NaCl flux, and LaTiO2N crystals were obtained by subsequent nitridation under NH3 flow. The TEM analysis indicated that the flux-grown platelike La2Ti2O7 crystals are single-crystalline growing along the a axis. The shapes and sizes of the LaTiO2N crystals were almost unchanged from the La2Ti2O7 precursor. In addition, LaTiO2N crystals remained single-crystalline with a porous nanostructure. The optical absorption edges of the La2Ti2O7 and LaTiO2N crystals were approximately 320 and 600 nm.
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U2 - 10.1021/cg5010006
DO - 10.1021/cg5010006
M3 - Article
AN - SCOPUS:84920768711
SN - 1528-7483
VL - 15
SP - 124
EP - 128
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 1
ER -