Chiral coordinating agent-based enantiocontrol in carbanion reactions

K. Tomooka

doi:10.5059/yukigoseikyokaishi.59.322

Chiral coordinating agent-based enantiocontrol in carbanion reactions

K. Tomooka

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

We have been exploring the various enantioselective carbanion reactions induced by the chiral coordinating agent-based asymmetric lithiation protocol. Disclosed herein are the enantioselective carbanion cyclization, S_E2 reaction of benzyl lithium, [2,3]- and [1,2]-Wittig rearrangement via the asymmetric lithiation with BuLi complexed with (-)-sparteien or chiral bisoxazoline, as a ligand.

Original language	English
Pages (from-to)	322-330
Number of pages	9
Journal	Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
Volume	59
Issue number	4
DOIs	https://doi.org/10.5059/yukigoseikyokaishi.59.322
Publication status	Published - 2001
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.5059/yukigoseikyokaishi.59.322

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abstract = "We have been exploring the various enantioselective carbanion reactions induced by the chiral coordinating agent-based asymmetric lithiation protocol. Disclosed herein are the enantioselective carbanion cyclization, SE2 reaction of benzyl lithium, [2,3]- and [1,2]-Wittig rearrangement via the asymmetric lithiation with BuLi complexed with (-)-sparteien or chiral bisoxazoline, as a ligand.",

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AB - We have been exploring the various enantioselective carbanion reactions induced by the chiral coordinating agent-based asymmetric lithiation protocol. Disclosed herein are the enantioselective carbanion cyclization, SE2 reaction of benzyl lithium, [2,3]- and [1,2]-Wittig rearrangement via the asymmetric lithiation with BuLi complexed with (-)-sparteien or chiral bisoxazoline, as a ligand.

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JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry

JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry

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ER -

Chiral coordinating agent-based enantiocontrol in carbanion reactions

Abstract

All Science Journal Classification (ASJC) codes

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