Chemical studies of Mo and W in preparation of a seaborgium (Sg) reduction experiment using MDG, FEC, and SISAK

A. Toyoshima; K. Ooe; S. Miyashita; M. Asai; M. F. Attallah; N. Goto; N. S. Gupta; H. Haba; M. Huang; J. Kanaya; Y. Kaneya; Y. Kasamatsu; Y. Kitatsuji; Y. Kitayama; K. Koga; Y. Komori; T. Koyama; J. V. Kratz; H. V. Lerum; Y. Oshimi; V. Pershina; D. Sato; T. K. Sato; Y. Shigekawa; A. Shinohara; A. Tanaka; K. Tsukada; S. Tsuto; T. Yokokita; A. Yokoyama; J. P. Omtvedt; Y. Nagame; M. Schädel

doi:10.1007/s10967-014-3438-x

Chemical studies of Mo and W in preparation of a seaborgium (Sg) reduction experiment using MDG, FEC, and SISAK

A. Toyoshima, K. Ooe, S. Miyashita, M. Asai, M. F. Attallah, N. Goto, N. S. Gupta, H. Haba, M. Huang, J. Kanaya, Y. Kaneya, Y. Kasamatsu, Y. Kitatsuji, Y. Kitayama, K. Koga, Y. Komori, T. Koyama, J. V. Kratz, H. V. Lerum, Y. OshimiV. Pershina, D. Sato, T. K. Sato, Y. Shigekawa, A. Shinohara, A. Tanaka, K. Tsukada, S. Tsuto, T. Yokokita, A. Yokoyama, J. P. Omtvedt, Y. Nagame, M. Schädel

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Abstract

The extraction and reduction behavior of Mo and W, lighter homologs of Sg, was studied in continuous on-line experiments at the JAEA tandem accelerator to develop a new chemistry assembly consisting of a membrane degasser (MDG), a flow electrolytic column (FEC), and the continuous liquid–liquid extraction apparatus (SISAK). Extraction yields of Mo and W from 0.1 M HCl/0.9 M LiCl into 4-isopropyltropolone (hinokitiol, HT) in toluene were investigated. In the reduction experiment, Mo(VI) was successfully reduced to a lower oxidation state while W(VI) showed no reduction under the given conditions.

Original language	English
Pages (from-to)	1169-1172
Number of pages	4
Journal	Journal of Radioanalytical and Nuclear Chemistry
Volume	303
Issue number	2
DOIs	https://doi.org/10.1007/s10967-014-3438-x
Publication status	Published - Feb 2015
Externally published	Yes

All Science Journal Classification (ASJC) codes

Analytical Chemistry
Nuclear Energy and Engineering
Radiology Nuclear Medicine and imaging
Pollution
Spectroscopy
Public Health, Environmental and Occupational Health
Health, Toxicology and Mutagenesis

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1007/s10967-014-3438-x

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Toyoshima, A., Ooe, K., Miyashita, S., Asai, M., Attallah, M. F., Goto, N., Gupta, N. S., Haba, H., Huang, M., Kanaya, J., Kaneya, Y., Kasamatsu, Y., Kitatsuji, Y., Kitayama, Y., Koga, K., Komori, Y., Koyama, T., Kratz, J. V., Lerum, H. V., ... Schädel, M. (2015). Chemical studies of Mo and W in preparation of a seaborgium (Sg) reduction experiment using MDG, FEC, and SISAK. Journal of Radioanalytical and Nuclear Chemistry, 303(2), 1169-1172. https://doi.org/10.1007/s10967-014-3438-x

Toyoshima, A, Ooe, K, Miyashita, S, Asai, M, Attallah, MF, Goto, N, Gupta, NS, Haba, H, Huang, M, Kanaya, J, Kaneya, Y, Kasamatsu, Y, Kitatsuji, Y, Kitayama, Y, Koga, K, Komori, Y, Koyama, T, Kratz, JV, Lerum, HV, Oshimi, Y, Pershina, V, Sato, D, Sato, TK, Shigekawa, Y, Shinohara, A, Tanaka, A, Tsukada, K, Tsuto, S, Yokokita, T, Yokoyama, A, Omtvedt, JP, Nagame, Y & Schädel, M 2015, 'Chemical studies of Mo and W in preparation of a seaborgium (Sg) reduction experiment using MDG, FEC, and SISAK', Journal of Radioanalytical and Nuclear Chemistry, vol. 303, no. 2, pp. 1169-1172. https://doi.org/10.1007/s10967-014-3438-x

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title = "Chemical studies of Mo and W in preparation of a seaborgium (Sg) reduction experiment using MDG, FEC, and SISAK",

abstract = "The extraction and reduction behavior of Mo and W, lighter homologs of Sg, was studied in continuous on-line experiments at the JAEA tandem accelerator to develop a new chemistry assembly consisting of a membrane degasser (MDG), a flow electrolytic column (FEC), and the continuous liquid–liquid extraction apparatus (SISAK). Extraction yields of Mo and W from 0.1 M HCl/0.9 M LiCl into 4-isopropyltropolone (hinokitiol, HT) in toluene were investigated. In the reduction experiment, Mo(VI) was successfully reduced to a lower oxidation state while W(VI) showed no reduction under the given conditions.",

author = "A. Toyoshima and K. Ooe and S. Miyashita and M. Asai and Attallah, {M. F.} and N. Goto and Gupta, {N. S.} and H. Haba and M. Huang and J. Kanaya and Y. Kaneya and Y. Kasamatsu and Y. Kitatsuji and Y. Kitayama and K. Koga and Y. Komori and T. Koyama and Kratz, {J. V.} and Lerum, {H. V.} and Y. Oshimi and V. Pershina and D. Sato and Sato, {T. K.} and Y. Shigekawa and A. Shinohara and A. Tanaka and K. Tsukada and S. Tsuto and T. Yokokita and A. Yokoyama and Omtvedt, {J. P.} and Y. Nagame and M. Sch{\"a}del",

note = "Publisher Copyright: {\textcopyright} 2014, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2015",

month = feb,

doi = "10.1007/s10967-014-3438-x",

language = "English",

volume = "303",

pages = "1169--1172",

journal = "Journal of Radioanalytical and Nuclear Chemistry",

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T1 - Chemical studies of Mo and W in preparation of a seaborgium (Sg) reduction experiment using MDG, FEC, and SISAK

AU - Toyoshima, A.

AU - Ooe, K.

AU - Miyashita, S.

AU - Asai, M.

AU - Attallah, M. F.

AU - Goto, N.

AU - Gupta, N. S.

AU - Haba, H.

AU - Huang, M.

AU - Kanaya, J.

AU - Kaneya, Y.

AU - Kasamatsu, Y.

AU - Kitatsuji, Y.

AU - Kitayama, Y.

AU - Koga, K.

AU - Komori, Y.

AU - Koyama, T.

AU - Kratz, J. V.

AU - Lerum, H. V.

AU - Oshimi, Y.

AU - Pershina, V.

AU - Sato, D.

AU - Sato, T. K.

AU - Shigekawa, Y.

AU - Shinohara, A.

AU - Tanaka, A.

AU - Tsukada, K.

AU - Tsuto, S.

AU - Yokokita, T.

AU - Yokoyama, A.

AU - Omtvedt, J. P.

AU - Nagame, Y.

AU - Schädel, M.

PY - 2015/2

Y1 - 2015/2

N2 - The extraction and reduction behavior of Mo and W, lighter homologs of Sg, was studied in continuous on-line experiments at the JAEA tandem accelerator to develop a new chemistry assembly consisting of a membrane degasser (MDG), a flow electrolytic column (FEC), and the continuous liquid–liquid extraction apparatus (SISAK). Extraction yields of Mo and W from 0.1 M HCl/0.9 M LiCl into 4-isopropyltropolone (hinokitiol, HT) in toluene were investigated. In the reduction experiment, Mo(VI) was successfully reduced to a lower oxidation state while W(VI) showed no reduction under the given conditions.

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IS - 2

ER -

Chemical studies of Mo and W in preparation of a seaborgium (Sg) reduction experiment using MDG, FEC, and SISAK

Abstract

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