Chemical modification of diamond surface with CH3(CH2)nCOOH using benzoyl peroxide

Toshiki Tsubota; Shunsuke Tanii; Shintaro Ida; Masanori Nagata; Yasumichi Matsumoto

doi:10.1039/b210248j

Chemical modification of diamond surface with CH3(CH2)nCOOH using benzoyl peroxide

Toshiki Tsubota, Shunsuke Tanii, Shintaro Ida, Masanori Nagata, Yasumichi Matsumoto

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The chemical reactivity of a hydrogenated diamond surface with carboxylic acid [HCOOH, CH₃(CH₂)_nCOOH (0 < n < 16)] in benzoyl peroxide containing solvent was investigated. The diamond surface modified with acetic acid was stable against severe conditions. The chemical reaction rate of the modification of the diamond surface was calculated based on experimental results. The peak intensity assigned to the C-H bond was determined by the kind of carboxylic acid used. The chemical reaction described in this study is very interesting because it can be used to design the chemical condition of the diamond surface. This chemical reaction constitutes a promising method for chemically modifying the diamond surface.

Original language	English
Pages (from-to)	1474-1480
Number of pages	7
Journal	Physical Chemistry Chemical Physics
Volume	5
Issue number	7
DOIs	https://doi.org/10.1039/b210248j
Publication status	Published - Apr 1 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics

Access to Document

10.1039/b210248j

Cite this

@article{c6f731556bac46a7861f0a7d7e6c5e81,

title = "Chemical modification of diamond surface with CH3(CH2)nCOOH using benzoyl peroxide",

abstract = "The chemical reactivity of a hydrogenated diamond surface with carboxylic acid [HCOOH, CH3(CH2)nCOOH (0 < n < 16)] in benzoyl peroxide containing solvent was investigated. The diamond surface modified with acetic acid was stable against severe conditions. The chemical reaction rate of the modification of the diamond surface was calculated based on experimental results. The peak intensity assigned to the C-H bond was determined by the kind of carboxylic acid used. The chemical reaction described in this study is very interesting because it can be used to design the chemical condition of the diamond surface. This chemical reaction constitutes a promising method for chemically modifying the diamond surface.",

author = "Toshiki Tsubota and Shunsuke Tanii and Shintaro Ida and Masanori Nagata and Yasumichi Matsumoto",

year = "2003",

month = apr,

day = "1",

doi = "10.1039/b210248j",

language = "English",

volume = "5",

pages = "1474--1480",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - Chemical modification of diamond surface with CH3(CH2)nCOOH using benzoyl peroxide

AU - Tsubota, Toshiki

AU - Tanii, Shunsuke

AU - Ida, Shintaro

AU - Nagata, Masanori

AU - Matsumoto, Yasumichi

PY - 2003/4/1

Y1 - 2003/4/1

N2 - The chemical reactivity of a hydrogenated diamond surface with carboxylic acid [HCOOH, CH3(CH2)nCOOH (0 < n < 16)] in benzoyl peroxide containing solvent was investigated. The diamond surface modified with acetic acid was stable against severe conditions. The chemical reaction rate of the modification of the diamond surface was calculated based on experimental results. The peak intensity assigned to the C-H bond was determined by the kind of carboxylic acid used. The chemical reaction described in this study is very interesting because it can be used to design the chemical condition of the diamond surface. This chemical reaction constitutes a promising method for chemically modifying the diamond surface.

AB - The chemical reactivity of a hydrogenated diamond surface with carboxylic acid [HCOOH, CH3(CH2)nCOOH (0 < n < 16)] in benzoyl peroxide containing solvent was investigated. The diamond surface modified with acetic acid was stable against severe conditions. The chemical reaction rate of the modification of the diamond surface was calculated based on experimental results. The peak intensity assigned to the C-H bond was determined by the kind of carboxylic acid used. The chemical reaction described in this study is very interesting because it can be used to design the chemical condition of the diamond surface. This chemical reaction constitutes a promising method for chemically modifying the diamond surface.

UR - http://www.scopus.com/inward/record.url?scp=0037383674&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037383674&partnerID=8YFLogxK

U2 - 10.1039/b210248j

DO - 10.1039/b210248j

M3 - Article

AN - SCOPUS:0037383674

SN - 1463-9076

VL - 5

SP - 1474

EP - 1480

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 7

ER -

Chemical modification of diamond surface with CH3(CH2)nCOOH using benzoyl peroxide

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this