TY - JOUR
T1 - Charge separation on the micelle surface as evidence for a multi-step hydrogen transfer mechanism in NADH model reduction
AU - Shinkai, Seiji
AU - Tsuno, Takaharu
AU - Manabe, Osamu
PY - 1982
Y1 - 1982
N2 - Reductive desulphonation of 2,4,6-trinitrobenzenesulphonate by N-dodecyl-1 -benzyl-1,4-dihydronicotinamide bound to the sodium dodecyl sulphate micelle in D2O solution gave 1,3,5-trinitrobenzene which contained 4.6-5.1% of deuterium; the result indicates that the reaction proceeds through multi-step hydrogen transfer via a radical ion-pair intermediate and the micelle surface is capable of dissociating the radical ion pair.
AB - Reductive desulphonation of 2,4,6-trinitrobenzenesulphonate by N-dodecyl-1 -benzyl-1,4-dihydronicotinamide bound to the sodium dodecyl sulphate micelle in D2O solution gave 1,3,5-trinitrobenzene which contained 4.6-5.1% of deuterium; the result indicates that the reaction proceeds through multi-step hydrogen transfer via a radical ion-pair intermediate and the micelle surface is capable of dissociating the radical ion pair.
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U2 - 10.1039/c39820000592
DO - 10.1039/c39820000592
M3 - Article
AN - SCOPUS:37049093280
SN - 0022-4936
SP - 592
EP - 594
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 11
ER -