Charge-discharge Mechanism of LiCoPO_4 Cathode for Rechargeable Lithium Batteries

Shigeto Okada; Sho-ichiro Sawa; Yasushi Uebou; Minato Egashira; Jun-ichi Yamaki; Mitsuharu Tabuchi; Hironori Kobayashi; Kohei Fukumi; Hiroyuki Kageyama

doi:10.5796/electrochemistry.71.1136

Charge-discharge Mechanism of LiCoPO_4 Cathode for Rechargeable Lithium Batteries

Shigeto Okada, Sho-ichiro Sawa, Yasushi Uebou, Minato Egashira, Jun-ichi Yamaki, Mitsuharu Tabuchi, Hironori Kobayashi, Kohei Fukumi, Hiroyuki Kageyama

Department of Advanced Device Materials

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of ordered-olivine LiCoPO4 was identified by neutron diffraction measurements. A 4.8 V discharge profile was demonstrated using coin-type cells. XAFS and magnetic measurements indicated that the high-voltage plateau of Li1−xCoPO4 corresponds to the Co2+/Co3+ redox reaction.

Original language	English
Pages (from-to)	1136-1138
Number of pages	3
Journal	Electrochemistry
Volume	71
Issue number	12
DOIs	https://doi.org/10.5796/electrochemistry.71.1136
Publication status	Published - Dec 5 2003

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10.5796/electrochemistry.71.1136

https://doi.org/10.5796/electrochemistry.71.1136

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title = "Charge-discharge Mechanism of LiCoPO_4 Cathode for Rechargeable Lithium Batteries",

abstract = "The structure of ordered-olivine LiCoPO4 was identified by neutron diffraction measurements. A 4.8 V discharge profile was demonstrated using coin-type cells. XAFS and magnetic measurements indicated that the high-voltage plateau of Li1−xCoPO4 corresponds to the Co2+/Co3+ redox reaction.",

author = "Shigeto Okada and Sho-ichiro Sawa and Yasushi Uebou and Minato Egashira and Jun-ichi Yamaki and Mitsuharu Tabuchi and Hironori Kobayashi and Kohei Fukumi and Hiroyuki Kageyama",

year = "2003",

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doi = "10.5796/electrochemistry.71.1136",

language = "English",

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TY - JOUR

T1 - Charge-discharge Mechanism of LiCoPO_4 Cathode for Rechargeable Lithium Batteries

AU - Okada, Shigeto

AU - Sawa, Sho-ichiro

AU - Uebou, Yasushi

AU - Egashira, Minato

AU - Yamaki, Jun-ichi

AU - Tabuchi, Mitsuharu

AU - Kobayashi, Hironori

AU - Fukumi, Kohei

AU - Kageyama, Hiroyuki

PY - 2003/12/5

Y1 - 2003/12/5

N2 - The structure of ordered-olivine LiCoPO4 was identified by neutron diffraction measurements. A 4.8 V discharge profile was demonstrated using coin-type cells. XAFS and magnetic measurements indicated that the high-voltage plateau of Li1−xCoPO4 corresponds to the Co2+/Co3+ redox reaction.

AB - The structure of ordered-olivine LiCoPO4 was identified by neutron diffraction measurements. A 4.8 V discharge profile was demonstrated using coin-type cells. XAFS and magnetic measurements indicated that the high-voltage plateau of Li1−xCoPO4 corresponds to the Co2+/Co3+ redox reaction.

U2 - 10.5796/electrochemistry.71.1136

DO - 10.5796/electrochemistry.71.1136

M3 - Article

SN - 1344-3542

VL - 71

SP - 1136

EP - 1138

JO - Electrochemistry

JF - Electrochemistry

IS - 12

ER -

Charge-discharge Mechanism of LiCoPO_4 Cathode for Rechargeable Lithium Batteries

Abstract

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