Characterizations of interlayer organic-inorganic nanohybrid of molybdenum trioxide with polyaniline and poly(o-anisidine)

Toshio Itoh; Ichiro Matsubara; Woosuck Shin; Noriya Izu; Maiko Nishibori

doi:10.1016/j.matchemphys.2008.01.024

Characterizations of interlayer organic-inorganic nanohybrid of molybdenum trioxide with polyaniline and poly(o-anisidine)

Toshio Itoh, Ichiro Matsubara, Woosuck Shin, Noriya Izu, Maiko Nishibori

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Characterizations of layered MoO₃ host with interlayer polyaniline (PANI) and poly(o-anisidine) (PoANIS), i.e. (PANI)_xMoO₃ and (PoANIS)_xMoO₃, respectively, have been carried out by means of X-ray diffraction (XRD), infrared (IR) spectra, thermogravimetry (TG), and solid-state nuclear magnetic resonance (NMR) analyses. The guest organic components, i.e. PANI and PoANIS, are accommodated into MoO₃ interlayers by ion-exchange process. From these detailed characterization studies, it is found that the interlayer PANI and PoANIS chains have neutralized units as well as cationic units. Moreover, the (PANI)_xMoO₃ and (PoANIS)_xMoO₃ hybrids have enough interlayer spaces due to almost perpendicular orientation of benzene ring into PANI and PoANIS chains to the MoO₃ layer.

Original language	English
Pages (from-to)	115-119
Number of pages	5
Journal	Materials Chemistry and Physics
Volume	110
Issue number	1
DOIs	https://doi.org/10.1016/j.matchemphys.2008.01.024
Publication status	Published - Jul 15 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics

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10.1016/j.matchemphys.2008.01.024

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@article{8824ad45e626483183eef9f0d5e5fccb,

title = "Characterizations of interlayer organic-inorganic nanohybrid of molybdenum trioxide with polyaniline and poly(o-anisidine)",

abstract = "Characterizations of layered MoO3 host with interlayer polyaniline (PANI) and poly(o-anisidine) (PoANIS), i.e. (PANI)xMoO3 and (PoANIS)xMoO3, respectively, have been carried out by means of X-ray diffraction (XRD), infrared (IR) spectra, thermogravimetry (TG), and solid-state nuclear magnetic resonance (NMR) analyses. The guest organic components, i.e. PANI and PoANIS, are accommodated into MoO3 interlayers by ion-exchange process. From these detailed characterization studies, it is found that the interlayer PANI and PoANIS chains have neutralized units as well as cationic units. Moreover, the (PANI)xMoO3 and (PoANIS)xMoO3 hybrids have enough interlayer spaces due to almost perpendicular orientation of benzene ring into PANI and PoANIS chains to the MoO3 layer.",

author = "Toshio Itoh and Ichiro Matsubara and Woosuck Shin and Noriya Izu and Maiko Nishibori",

note = "Funding Information: This work was supported by New Energy and Industrial Technology Development Organization (NEDO). We would like to express our thanks for their kind supports.",

year = "2008",

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doi = "10.1016/j.matchemphys.2008.01.024",

language = "English",

volume = "110",

pages = "115--119",

journal = "Materials Chemistry and Physics",

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T1 - Characterizations of interlayer organic-inorganic nanohybrid of molybdenum trioxide with polyaniline and poly(o-anisidine)

AU - Itoh, Toshio

AU - Matsubara, Ichiro

AU - Shin, Woosuck

AU - Izu, Noriya

AU - Nishibori, Maiko

N1 - Funding Information: This work was supported by New Energy and Industrial Technology Development Organization (NEDO). We would like to express our thanks for their kind supports.

PY - 2008/7/15

Y1 - 2008/7/15

N2 - Characterizations of layered MoO3 host with interlayer polyaniline (PANI) and poly(o-anisidine) (PoANIS), i.e. (PANI)xMoO3 and (PoANIS)xMoO3, respectively, have been carried out by means of X-ray diffraction (XRD), infrared (IR) spectra, thermogravimetry (TG), and solid-state nuclear magnetic resonance (NMR) analyses. The guest organic components, i.e. PANI and PoANIS, are accommodated into MoO3 interlayers by ion-exchange process. From these detailed characterization studies, it is found that the interlayer PANI and PoANIS chains have neutralized units as well as cationic units. Moreover, the (PANI)xMoO3 and (PoANIS)xMoO3 hybrids have enough interlayer spaces due to almost perpendicular orientation of benzene ring into PANI and PoANIS chains to the MoO3 layer.

AB - Characterizations of layered MoO3 host with interlayer polyaniline (PANI) and poly(o-anisidine) (PoANIS), i.e. (PANI)xMoO3 and (PoANIS)xMoO3, respectively, have been carried out by means of X-ray diffraction (XRD), infrared (IR) spectra, thermogravimetry (TG), and solid-state nuclear magnetic resonance (NMR) analyses. The guest organic components, i.e. PANI and PoANIS, are accommodated into MoO3 interlayers by ion-exchange process. From these detailed characterization studies, it is found that the interlayer PANI and PoANIS chains have neutralized units as well as cationic units. Moreover, the (PANI)xMoO3 and (PoANIS)xMoO3 hybrids have enough interlayer spaces due to almost perpendicular orientation of benzene ring into PANI and PoANIS chains to the MoO3 layer.

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VL - 110

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JO - Materials Chemistry and Physics

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Characterizations of interlayer organic-inorganic nanohybrid of molybdenum trioxide with polyaniline and poly(o-anisidine)

Abstract

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