Changes in molecular assembly of mesophase pitches at higher temperatures, especially at spinning temperatures were examined using a high temperature X-ray diffractometer, a fused 13C-NMR and an optical microscope with hot stage. Although anisotropic contents of all mesophase pitches used in the present study were 100 vol%, it was found that their assembly of constituent molecules even at room temperature was very different. Such a planar stacking changed markedly at higher temperature. Lc decreased with rising temperature at higher temperature than softening temperature, maintaining the ordered carbon content and the anisotropic content of 100 vol%.
|Number of pages||2|
|Journal||Extended Abstracts and Program - Biennial Conference on Carbon|
|Publication status||Published - 1991|
|Event||20th Biennial Conference on Carbon - Santa Barbara, CA, USA|
Duration: Jun 23 1991 → Jun 28 1991
All Science Journal Classification (ASJC) codes