TY - JOUR
T1 - C–H Arylation of Benzene with Aryl Halides using H2 and a Water-Soluble Rh-Based Electron Storage Catalyst
AU - Yatabe, Takeshi
AU - Tome, Tamon
AU - Takahashi, Yukina
AU - Matsumoto, Takahiro
AU - Yoon, Ki Seok
AU - Nakai, Hidetaka
AU - Ogo, Seiji
N1 - Funding Information:
This paper is dedicated to the memory of Research Supervisor of CREST, Professor Emeritus Jun‐ichi Yoshida. This work was supported by JST CREST Grant Number JPMJCR18R2, Japan, JSPS KAKENHI Grant Numbers JP26000008 (Specially Promoted Research) and JP19K05503.
Publisher Copyright:
© 2021 Wiley-VCH GmbH
PY - 2021/12/9
Y1 - 2021/12/9
N2 - This paper reports the first example of C−H arylation of benzene under mild conditions, using H2 as an electron source {turnover numbers (TONs)=0.7–2.0 for 24 h}. The reaction depends on a Rh-based electron storage catalyst, and proceeds at room temperature and in aqueous solution. Furthermore, the H2 is inactive during the radical transfer step, greatly reducing unwanted side reactions.
AB - This paper reports the first example of C−H arylation of benzene under mild conditions, using H2 as an electron source {turnover numbers (TONs)=0.7–2.0 for 24 h}. The reaction depends on a Rh-based electron storage catalyst, and proceeds at room temperature and in aqueous solution. Furthermore, the H2 is inactive during the radical transfer step, greatly reducing unwanted side reactions.
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U2 - 10.1002/chem.202102735
DO - 10.1002/chem.202102735
M3 - Article
AN - SCOPUS:85117806714
SN - 0947-6539
VL - 27
SP - 17326
EP - 17330
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 69
ER -