Cationic Co(III)(salen)-catalyzed enantioselective Baeyer-Villiger oxidation of 3-arylcyclobutanones using hydrogen peroxide as a terminal oxidant

Tatsuya Uchida; Tsutomu Katsuki

doi:10.1016/S0040-4039(01)01445-9

Cationic Co(III)(salen)-catalyzed enantioselective Baeyer-Villiger oxidation of 3-arylcyclobutanones using hydrogen peroxide as a terminal oxidant

Tatsuya Uchida, Tsutomu Katsuki

Division for Experimental Natural Science

Research output: Contribution to journal › Article › peer-review

107 Citations (Scopus)

Abstract

A cationic Co(III)(salen) complex of cis-β-structure was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger reaction of 3-substituted cyclobutanone using hydrogen peroxide as a terminal oxidant. Good enantioselectivity up to 78% ee was achieved.

Original language	English
Pages (from-to)	6911-6914
Number of pages	4
Journal	Tetrahedron Letters
Volume	42
Issue number	39
DOIs	https://doi.org/10.1016/S0040-4039(01)01445-9
Publication status	Published - Sept 24 2001

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)01445-9

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abstract = "A cationic Co(III)(salen) complex of cis-β-structure was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger reaction of 3-substituted cyclobutanone using hydrogen peroxide as a terminal oxidant. Good enantioselectivity up to 78% ee was achieved.",

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AU - Uchida, Tatsuya

AU - Katsuki, Tsutomu

PY - 2001/9/24

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N2 - A cationic Co(III)(salen) complex of cis-β-structure was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger reaction of 3-substituted cyclobutanone using hydrogen peroxide as a terminal oxidant. Good enantioselectivity up to 78% ee was achieved.

AB - A cationic Co(III)(salen) complex of cis-β-structure was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger reaction of 3-substituted cyclobutanone using hydrogen peroxide as a terminal oxidant. Good enantioselectivity up to 78% ee was achieved.

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DO - 10.1016/S0040-4039(01)01445-9

M3 - Article

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SN - 0040-4039

VL - 42

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JO - Tetrahedron Letters

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ER -

Cationic Co(III)(salen)-catalyzed enantioselective Baeyer-Villiger oxidation of 3-arylcyclobutanones using hydrogen peroxide as a terminal oxidant

Abstract

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