Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

Ryosuke Kawakami; Shogo Kuriyama; Hiromasa Tanaka; Kazuya Arashiba; Asuka Konomi; Kazunari Nakajima; Kazunari Yoshizawa; Yoshiaki Nishibayashi

doi:10.1039/c9cc06896a

Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

Ryosuke Kawakami, Shogo Kuriyama, Hiromasa Tanaka, Kazuya Arashiba, Asuka Konomi, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. This is the first successful example of rhodium-catalysed dinitrogen reduction under mild reaction conditions.

Original language	English
Pages (from-to)	14886-14889
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	99
DOIs	https://doi.org/10.1039/c9cc06896a
Publication status	Published - 2019

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c9cc06896a

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title = "Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand",

abstract = "Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. This is the first successful example of rhodium-catalysed dinitrogen reduction under mild reaction conditions.",

author = "Ryosuke Kawakami and Shogo Kuriyama and Hiromasa Tanaka and Kazuya Arashiba and Asuka Konomi and Kazunari Nakajima and Kazunari Yoshizawa and Yoshiaki Nishibayashi",

note = "Funding Information: The present project was supported by CREST, JST (Grant JPMJCR1541). We acknowledge Grants-in-Aid for Scientific Research (Grants JP17H01201, JP15H05798, JP18K19093, JP18K05148, and JP19K23645) from JSPS and MEXT. Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc06896a",

language = "English",

volume = "55",

pages = "14886--14889",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "99",

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TY - JOUR

T1 - Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

AU - Kawakami, Ryosuke

AU - Kuriyama, Shogo

AU - Tanaka, Hiromasa

AU - Arashiba, Kazuya

AU - Konomi, Asuka

AU - Nakajima, Kazunari

AU - Yoshizawa, Kazunari

AU - Nishibayashi, Yoshiaki

N1 - Funding Information: The present project was supported by CREST, JST (Grant JPMJCR1541). We acknowledge Grants-in-Aid for Scientific Research (Grants JP17H01201, JP15H05798, JP18K19093, JP18K05148, and JP19K23645) from JSPS and MEXT. Publisher Copyright: This journal is © The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. This is the first successful example of rhodium-catalysed dinitrogen reduction under mild reaction conditions.

AB - Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. This is the first successful example of rhodium-catalysed dinitrogen reduction under mild reaction conditions.

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U2 - 10.1039/c9cc06896a

DO - 10.1039/c9cc06896a

M3 - Article

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AN - SCOPUS:85076330293

SN - 1359-7345

VL - 55

SP - 14886

EP - 14889

JO - Chemical Communications

JF - Chemical Communications

IS - 99

ER -

Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

Abstract

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