Catalytic functionalization of methyl group on silicon: Iridium-catalyzed C(sp3)-H borylation of methylchlorosilanes

Toshimichi Ohmura; Takeru Torigoe; Michinori Suginome

doi:10.1021/ja307956w

Catalytic functionalization of methyl group on silicon: Iridium-catalyzed C(sp³)-H borylation of methylchlorosilanes

Toshimichi Ohmura, Takeru Torigoe, Michinori Suginome

Research output: Contribution to journal › Article › peer-review

77 Citations (Scopus)

Abstract

A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 °C, giving (borylmethyl)chlorosilanes selectively.

Original language	English
Pages (from-to)	17416-17419
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	42
DOIs	https://doi.org/10.1021/ja307956w
Publication status	Published - Oct 24 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja307956w

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title = "Catalytic functionalization of methyl group on silicon: Iridium-catalyzed C(sp3)-H borylation of methylchlorosilanes",

abstract = "A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 °C, giving (borylmethyl)chlorosilanes selectively.",

author = "Toshimichi Ohmura and Takeru Torigoe and Michinori Suginome",

year = "2012",

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doi = "10.1021/ja307956w",

language = "English",

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AU - Ohmura, Toshimichi

AU - Torigoe, Takeru

AU - Suginome, Michinori

PY - 2012/10/24

Y1 - 2012/10/24

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AB - A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 °C, giving (borylmethyl)chlorosilanes selectively.

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Catalytic functionalization of methyl group on silicon: Iridium-catalyzed C(sp³)-H borylation of methylchlorosilanes

Abstract

All Science Journal Classification (ASJC) codes

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