@article{3f3c8cc335af4cb883eebe226a68469b,
title = "Catalytic Dehalogenation of Aryl Halides via Excited State Electron Transfer from the Co(I) State of B12 Complex",
abstract = "Reductive dehalogenation of aryl halides, bromobenzonitrile and iodobenzonitrile by the photo-excited B12 complex with the labile Co(I) oxidation state under anaerobic conditions was reported for the first time. A sub-pico second time-resolved spectroscopic analysis showed that the excited state of the B12 complex, ∗Co(I), has a 280 ps lifetime and the rate constants of electron transfer to the reactants (kET) are 3.6 ",
author = "Hisashi Shimakoshi and Keita Shichijo and Shiori Tominaga and Yoshio Hisaeda and Mamoru Fujitsuka and Tetsuro Majima",
note = "Funding Information: We express our gratitude to Professor Takahiro Matsumoto (Kyushu University, Japan) for fruitful discussion. This study was partially supported by a Grant-in-Aid for Scientific Research (B) (JP19H02735) from the Japan Society for the Promotion of Science (JSPS). A part of the study was performed under the Cooperative Research Program of “Network Joint Research Center for Materials and Devices: Dynamic Alliance for Open Innovation Bridging Human, Environment and Materials” (20193019 and 20203024). Publisher Copyright: {\textcopyright} 109, 3.3 Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = jul,
doi = "10.1246/cl.200241",
language = "English",
volume = "49",
pages = "820--822",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "The Chemical Society of Japan",
number = "7",
}