Catalytic asymmetric hydrogenation of naphthalenes

Ryoichi Kuwano; Ryuichi Morioka; Manabu Kashiwabara; Nao Kameyama

doi:10.1002/anie.201201153

Catalytic asymmetric hydrogenation of naphthalenes

Ryoichi Kuwano, Ryuichi Morioka, Manabu Kashiwabara, Nao Kameyama

Multidisciplinary chemistry

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

Vanishing aromaticity: A chiral ruthenium complex catalyzes the hydrogenation of 2,6- or 2,7-disubstituted naphthalenes to give chiral tetralins with up to 92 % ee. The chiral catalyst is applicable to the regio- and enantioselective reduction of 6-substituted 2-alkoxynaphthalenes and preferentially hydrogenates the alkoxy-substituted arene rings.

Original language	English
Pages (from-to)	4136-4139
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	17
DOIs	https://doi.org/10.1002/anie.201201153
Publication status	Published - Apr 23 2012

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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AU - Morioka, Ryuichi

AU - Kashiwabara, Manabu

AU - Kameyama, Nao

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Catalytic asymmetric hydrogenation of naphthalenes

Abstract

All Science Journal Classification (ASJC) codes

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