Catalyst design for iron-promoted reductions: An iron disilyl-dicarbonyl complex bearing weakly coordinating η2-(H-Si) moieties

Yusuke Sunada; Hironori Tsutsumi; Keisuke Shigeta; Ryota Yoshida; Toru Hashimoto; Hideo Nagashima

doi:10.1039/c3dt52598h

Catalyst design for iron-promoted reductions: An iron disilyl-dicarbonyl complex bearing weakly coordinating η²-(H-Si) moieties

Yusuke Sunada, Hironori Tsutsumi, Keisuke Shigeta, Ryota Yoshida, Toru Hashimoto, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

Iron disilyl dicarbonyl complex 1, in which two H-Si moieties of the 1,2-bis(dimethylsilyl)benzene ligand were coordinated to the iron center in an η²-(H-Si) fashion, was synthesized by the reaction of (η⁴-C₆H₈)Fe(CO)₃ with 2 equiv. of 1,2-bis(dimethylsilyl)benzene under photo-irradiation. Complex 1 demonstrated high catalytic activity toward the hydrogenation of alkenes, the hydrosilylation of alkenes and the reduction of carbonyl compounds.

Original language	English
Pages (from-to)	16687-16692
Number of pages	6
Journal	Dalton Transactions
Volume	42
Issue number	48
DOIs	https://doi.org/10.1039/c3dt52598h
Publication status	Published - Dec 28 2013

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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abstract = "Iron disilyl dicarbonyl complex 1, in which two H-Si moieties of the 1,2-bis(dimethylsilyl)benzene ligand were coordinated to the iron center in an η2-(H-Si) fashion, was synthesized by the reaction of (η4-C6H8)Fe(CO)3 with 2 equiv. of 1,2-bis(dimethylsilyl)benzene under photo-irradiation. Complex 1 demonstrated high catalytic activity toward the hydrogenation of alkenes, the hydrosilylation of alkenes and the reduction of carbonyl compounds.",

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T2 - An iron disilyl-dicarbonyl complex bearing weakly coordinating η2-(H-Si) moieties

AU - Sunada, Yusuke

AU - Tsutsumi, Hironori

AU - Shigeta, Keisuke

AU - Yoshida, Ryota

AU - Hashimoto, Toru

AU - Nagashima, Hideo

PY - 2013/12/28

Y1 - 2013/12/28

N2 - Iron disilyl dicarbonyl complex 1, in which two H-Si moieties of the 1,2-bis(dimethylsilyl)benzene ligand were coordinated to the iron center in an η2-(H-Si) fashion, was synthesized by the reaction of (η4-C6H8)Fe(CO)3 with 2 equiv. of 1,2-bis(dimethylsilyl)benzene under photo-irradiation. Complex 1 demonstrated high catalytic activity toward the hydrogenation of alkenes, the hydrosilylation of alkenes and the reduction of carbonyl compounds.

AB - Iron disilyl dicarbonyl complex 1, in which two H-Si moieties of the 1,2-bis(dimethylsilyl)benzene ligand were coordinated to the iron center in an η2-(H-Si) fashion, was synthesized by the reaction of (η4-C6H8)Fe(CO)3 with 2 equiv. of 1,2-bis(dimethylsilyl)benzene under photo-irradiation. Complex 1 demonstrated high catalytic activity toward the hydrogenation of alkenes, the hydrosilylation of alkenes and the reduction of carbonyl compounds.

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Catalyst design for iron-promoted reductions: An iron disilyl-dicarbonyl complex bearing weakly coordinating η²-(H-Si) moieties

Abstract

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