B12-TiO2 Hybrid Catalyst for Light-Driven Hydrogen Production and Hydrogenation of C-C Multiple Bonds

Hisashi Shimakoshi, Yoshio Hisaeda

    Research output: Contribution to journalArticlepeer-review

    37 Citations (Scopus)

    Abstract

    The B12-TiO2 hybrid catalyst mediates H2O reduction to form hydrogen under UV irradiation (turnover number of one per hour). The catalyst also mediates reductions of alkenes such as styrene derivatives and alkylacrylates (maximum turnover number of 100 per hour) under mild conditions of room temperature, ordinary pressure, and water or alcohol as solvent.

    Original languageEnglish
    Pages (from-to)1250-1253
    Number of pages4
    JournalChemPlusChem
    Volume79
    Issue number9
    DOIs
    Publication statusPublished - Sept 1 2014

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)

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