Bis{di-μ-isobutyrato-bis[cis-diammine-platinum(II)]} tetraperchlorate

Ken Sakai; Eri Ishigami

doi:10.1107/S160053680302782X

Bis{di-μ-isobutyrato-bis[cis-diammine-platinum(II)]} tetraperchlorate

Ken Sakai, Eri Ishigami

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The title compound, [Pt₂(μ-C₄O₂) ₂(NH₃)₄]₂(ClO₄) ₄, involves two independent diplatinum(II) units. For each unit, a pair of dimeric units located around an inversion center are associated with one another to give a tetranuclear Pt₄^II cation, in which the interdimer association is stabilized by four hydrogen bonds formed between the ammines and the butyrate O atoms. The intradimer and interdimer Pt-Pt distances within these tetraplatinum(II) chain cations are, respectively, 2.9881 (4) and 3.2619 (6) Å for one set of dimers, and 3.0246 (4) and 3.3049 (6) Å for the other set of dimers.

Original language	English
Pages (from-to)	m65-m68
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	1
DOIs	https://doi.org/10.1107/S160053680302782X
Publication status	Published - Jan 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S160053680302782X

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title = "Bis{di-μ-isobutyrato-bis[cis-diammine-platinum(II)]} tetraperchlorate",

abstract = "The title compound, [Pt2(μ-C4O2) 2(NH3)4]2(ClO4) 4, involves two independent diplatinum(II) units. For each unit, a pair of dimeric units located around an inversion center are associated with one another to give a tetranuclear Pt4II cation, in which the interdimer association is stabilized by four hydrogen bonds formed between the ammines and the butyrate O atoms. The intradimer and interdimer Pt-Pt distances within these tetraplatinum(II) chain cations are, respectively, 2.9881 (4) and 3.2619 (6) {\AA} for one set of dimers, and 3.0246 (4) and 3.3049 (6) {\AA} for the other set of dimers.",

author = "Ken Sakai and Eri Ishigami",

year = "2004",

month = jan,

doi = "10.1107/S160053680302782X",

language = "English",

volume = "60",

pages = "m65--m68",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "1",

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T1 - Bis{di-μ-isobutyrato-bis[cis-diammine-platinum(II)]} tetraperchlorate

AU - Sakai, Ken

AU - Ishigami, Eri

PY - 2004/1

Y1 - 2004/1

N2 - The title compound, [Pt2(μ-C4O2) 2(NH3)4]2(ClO4) 4, involves two independent diplatinum(II) units. For each unit, a pair of dimeric units located around an inversion center are associated with one another to give a tetranuclear Pt4II cation, in which the interdimer association is stabilized by four hydrogen bonds formed between the ammines and the butyrate O atoms. The intradimer and interdimer Pt-Pt distances within these tetraplatinum(II) chain cations are, respectively, 2.9881 (4) and 3.2619 (6) Å for one set of dimers, and 3.0246 (4) and 3.3049 (6) Å for the other set of dimers.

AB - The title compound, [Pt2(μ-C4O2) 2(NH3)4]2(ClO4) 4, involves two independent diplatinum(II) units. For each unit, a pair of dimeric units located around an inversion center are associated with one another to give a tetranuclear Pt4II cation, in which the interdimer association is stabilized by four hydrogen bonds formed between the ammines and the butyrate O atoms. The intradimer and interdimer Pt-Pt distances within these tetraplatinum(II) chain cations are, respectively, 2.9881 (4) and 3.2619 (6) Å for one set of dimers, and 3.0246 (4) and 3.3049 (6) Å for the other set of dimers.

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Bis{di-μ-isobutyrato-bis[cis-diammine-platinum(II)]} tetraperchlorate

Abstract

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