Bis[(2,3,6,7,12,13,16,17-octaethylporphycenato)oxomolybdenum(V)] hexamolybdate(VI)

Daisuke Maeda, Isao Aritome, Hisashi Shimakoshi, Yoshio Hisaeda

    Research output: Contribution to journalArticlepeer-review

    3 Citations (Scopus)

    Abstract

    The title compound, [Mo(C36H44N4)O] 2[Mo6O19], contains a five-coordinate molybdenum-porphycene cationic complex, accompanied by a centrosymmetric hexamolybdate counter-anion. This is the first structure for a molybdenum porphycene. The shape of the central N4 cavity is rectangular, enlarged lengthwise by metal coordination, and the mean short and long N⋯N distances defining the N4 cavity are 2.582(9) and 3.031(9), respectively.

    Original languageEnglish
    Pages (from-to)m1272-m1274
    JournalActa Crystallographica Section E: Structure Reports Online
    Volume62
    Issue number6
    DOIs
    Publication statusPublished - Jun 2006

    All Science Journal Classification (ASJC) codes

    • General Chemistry
    • General Materials Science
    • Condensed Matter Physics

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