Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) tetracyanoplatinate(II) dihydrate

Ken Sakai; Mina Mizota; Norinobu Akiyama

doi:10.1107/S1600536803028332

Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) tetracyanoplatinate(II) dihydrate

Ken Sakai, Mina Mizota, Norinobu Akiyama

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

In the title compound, [Pt(C₁₀H₈N₂)(C ₅H₆N₂)₂][Pt(CN)₄] ·-2H₂O, cations and anions alternate along the a axis, giving a one-dimensional chain of the Magnus green salt type. The electrostatic interactions between the divalent cations and anions, together with the π-π stacking associations between the 2,2′-bipyridine moieties, contribute to the stabilization of the crystal packing. Two different Pt⋯Pt distances [5.2034 (6) and 4.5599 (6) Å] alternate along the one-dimensional stack.

Original language	English
Pages (from-to)	m88-m90
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	1
DOIs	https://doi.org/10.1107/S1600536803028332
Publication status	Published - Jan 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) tetracyanoplatinate(II) dihydrate",

abstract = "In the title compound, [Pt(C10H8N2)(C 5H6N2)2][Pt(CN)4] ·-2H2O, cations and anions alternate along the a axis, giving a one-dimensional chain of the Magnus green salt type. The electrostatic interactions between the divalent cations and anions, together with the π-π stacking associations between the 2,2′-bipyridine moieties, contribute to the stabilization of the crystal packing. Two different Pt⋯Pt distances [5.2034 (6) and 4.5599 (6) {\AA}] alternate along the one-dimensional stack.",

author = "Ken Sakai and Mina Mizota and Norinobu Akiyama",

year = "2004",

month = jan,

doi = "10.1107/S1600536803028332",

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publisher = "International Union of Crystallography",

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T1 - Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) tetracyanoplatinate(II) dihydrate

AU - Sakai, Ken

AU - Mizota, Mina

AU - Akiyama, Norinobu

PY - 2004/1

Y1 - 2004/1

N2 - In the title compound, [Pt(C10H8N2)(C 5H6N2)2][Pt(CN)4] ·-2H2O, cations and anions alternate along the a axis, giving a one-dimensional chain of the Magnus green salt type. The electrostatic interactions between the divalent cations and anions, together with the π-π stacking associations between the 2,2′-bipyridine moieties, contribute to the stabilization of the crystal packing. Two different Pt⋯Pt distances [5.2034 (6) and 4.5599 (6) Å] alternate along the one-dimensional stack.

AB - In the title compound, [Pt(C10H8N2)(C 5H6N2)2][Pt(CN)4] ·-2H2O, cations and anions alternate along the a axis, giving a one-dimensional chain of the Magnus green salt type. The electrostatic interactions between the divalent cations and anions, together with the π-π stacking associations between the 2,2′-bipyridine moieties, contribute to the stabilization of the crystal packing. Two different Pt⋯Pt distances [5.2034 (6) and 4.5599 (6) Å] alternate along the one-dimensional stack.

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Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) tetracyanoplatinate(II) dihydrate

Abstract

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