Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) bis(oxalato)platinate(II) dihydrate

Ken Sakai; Norinobu Akiyama; Mina Mizota

doi:10.1107/S1600536803015770

Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) bis(oxalato)platinate(II) dihydrate

Ken Sakai, Norinobu Akiyama, Mina Mizota

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Cations and anions in [Pt(C₁₀H₈N₂)(C ₅H₆N₂)₂][Pt(C₂O ₄)₂]·-2H₂O stack alternately along the a axis, giving a one-dimensional chain of the Magnus's green salt type. Intrachain π-π-stacking interactions are achieved between the oxalate and the 2,2′-bipyridine moieties, where the plane-to-plane separations are 3.41 (7) and 3.46 (1) Å. Two different Pt⋯Pt distances [3.9294 (6) and 5.0302 (7) Å] alternate along the chain.

Original language	English
Pages (from-to)	m636-m638
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	8
DOIs	https://doi.org/10.1107/S1600536803015770
Publication status	Published - Aug 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) bis(oxalato)platinate(II) dihydrate",

abstract = "Cations and anions in [Pt(C10H8N2)(C 5H6N2)2][Pt(C2O 4)2]·-2H2O stack alternately along the a axis, giving a one-dimensional chain of the Magnus's green salt type. Intrachain π-π-stacking interactions are achieved between the oxalate and the 2,2′-bipyridine moieties, where the plane-to-plane separations are 3.41 (7) and 3.46 (1) {\AA}. Two different Pt⋯Pt distances [3.9294 (6) and 5.0302 (7) {\AA}] alternate along the chain.",

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year = "2003",

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doi = "10.1107/S1600536803015770",

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volume = "59",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) bis(oxalato)platinate(II) dihydrate

AU - Sakai, Ken

AU - Akiyama, Norinobu

AU - Mizota, Mina

PY - 2003/8

Y1 - 2003/8

N2 - Cations and anions in [Pt(C10H8N2)(C 5H6N2)2][Pt(C2O 4)2]·-2H2O stack alternately along the a axis, giving a one-dimensional chain of the Magnus's green salt type. Intrachain π-π-stacking interactions are achieved between the oxalate and the 2,2′-bipyridine moieties, where the plane-to-plane separations are 3.41 (7) and 3.46 (1) Å. Two different Pt⋯Pt distances [3.9294 (6) and 5.0302 (7) Å] alternate along the chain.

AB - Cations and anions in [Pt(C10H8N2)(C 5H6N2)2][Pt(C2O 4)2]·-2H2O stack alternately along the a axis, giving a one-dimensional chain of the Magnus's green salt type. Intrachain π-π-stacking interactions are achieved between the oxalate and the 2,2′-bipyridine moieties, where the plane-to-plane separations are 3.41 (7) and 3.46 (1) Å. Two different Pt⋯Pt distances [3.9294 (6) and 5.0302 (7) Å] alternate along the chain.

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Bis(2-aminopyridine)(2,2′-bipyridine)-platinum(II) bis(oxalato)platinate(II) dihydrate

Abstract

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