Bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate

Miho Hashioka; Ken Sakai; Taro Tsubomura

doi:10.1107/S0108270198004521

Bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate

Miho Hashioka, Ken Sakai, Taro Tsubomura

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A dinuclear palladium(I) complex bridged by two diphosphine ligands, bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate, [Pd₂Cl₂(C₂₅H₄₆P₂) ₂].2C₂H₃N, has been prepared, and the crystal structure determined. The two approximately square-planar ligand arrays show twisting, and the torsion angles are interpreted in terms of the steric factors between the diphosphine ligands.

Original language	English
Pages (from-to)	1244-1247
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	9
DOIs	https://doi.org/10.1107/S0108270198004521
Publication status	Published - Sept 15 1998
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry, Genetics and Molecular Biology(all)

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title = "Bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate",

abstract = "A dinuclear palladium(I) complex bridged by two diphosphine ligands, bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate, [Pd2Cl2(C25H46P2) 2].2C2H3N, has been prepared, and the crystal structure determined. The two approximately square-planar ligand arrays show twisting, and the torsion angles are interpreted in terms of the steric factors between the diphosphine ligands.",

author = "Miho Hashioka and Ken Sakai and Taro Tsubomura",

year = "1998",

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doi = "10.1107/S0108270198004521",

language = "English",

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journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

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T1 - Bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate

AU - Hashioka, Miho

AU - Sakai, Ken

AU - Tsubomura, Taro

PY - 1998/9/15

Y1 - 1998/9/15

N2 - A dinuclear palladium(I) complex bridged by two diphosphine ligands, bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate, [Pd2Cl2(C25H46P2) 2].2C2H3N, has been prepared, and the crystal structure determined. The two approximately square-planar ligand arrays show twisting, and the torsion angles are interpreted in terms of the steric factors between the diphosphine ligands.

AB - A dinuclear palladium(I) complex bridged by two diphosphine ligands, bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate, [Pd2Cl2(C25H46P2) 2].2C2H3N, has been prepared, and the crystal structure determined. The two approximately square-planar ligand arrays show twisting, and the torsion angles are interpreted in terms of the steric factors between the diphosphine ligands.

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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ER -

Bis[μ-methylenebis(dicyclohexylphosphine)-P:P′] bis[chloropalladium(I)](Pd - Pd) diacetonitrile solvate

Abstract

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