TY - JOUR
T1 - Bidirectional Chemo-Switching of Spin State in a Microporous Framework
AU - Ohba, Masaaki
AU - Yoneda, Ko
AU - Agusti, Gloria
AU - Muñoz, M. Carmen
AU - Gaspar, Ana B.
AU - Real, José A.
AU - Yamasaki, Mikio
AU - Ando, Hideo
AU - Nakao, Yoshihide
AU - Sakaki, Shigeyoshi
AU - Kitagawa, Susumu
PY - 2009/6/15
Y1 - 2009/6/15
N2 - The ins and outs of spin: Using the microporous coordination polymer {Fe(pz)[Pt(CN)4]} (1, pz=pyrazine), incorporating spin-crossover subunits, two-directional magnetic chemo-switching is achieved at room temperature. In situ magnetic measurements following guest vapor injection show that most guest molecules transform 1 from the low-spin (LS) state to the high-spin (HS) state, whereas CS2 uniquely causes the reverse HS-to-LS transition.
AB - The ins and outs of spin: Using the microporous coordination polymer {Fe(pz)[Pt(CN)4]} (1, pz=pyrazine), incorporating spin-crossover subunits, two-directional magnetic chemo-switching is achieved at room temperature. In situ magnetic measurements following guest vapor injection show that most guest molecules transform 1 from the low-spin (LS) state to the high-spin (HS) state, whereas CS2 uniquely causes the reverse HS-to-LS transition.
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U2 - 10.1002/anie.200806039
DO - 10.1002/anie.200806039
M3 - Article
C2 - 19294711
AN - SCOPUS:70349782147
SN - 1433-7851
VL - 48
SP - 4767
EP - 4771
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 26
ER -