Benzene ring trimer interactions modulate supramolecular structures

Tatsuki Morimoto; Hidemitsu Uno; Hiroyuki Furuta

doi:10.1002/anie.200604371

Benzene ring trimer interactions modulate supramolecular structures

Tatsuki Morimoto, Hidemitsu Uno, Hiroyuki Furuta

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

Ring a ring of benzenes: An unsubstituted N-confused metalloporphyrin forms both C₃- and C₁-symmetric trimers in solution, whereas its monophenyl-substituted analogue forms exclusively C₃-symmetric trimers (see picture) owing to significant stabilizing noncovalent interactions between the three phenyl groups, as evaluated both experimentally and theoretically. (Figure Presented).

Original language	English
Pages (from-to)	3672-3675
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	20
DOIs	https://doi.org/10.1002/anie.200604371
Publication status	Published - 2007

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200604371

Cite this

@article{ff2e802e2ece4617a3124777927db6e8,

title = "Benzene ring trimer interactions modulate supramolecular structures",

abstract = "Ring a ring of benzenes: An unsubstituted N-confused metalloporphyrin forms both C3- and C1-symmetric trimers in solution, whereas its monophenyl-substituted analogue forms exclusively C3-symmetric trimers (see picture) owing to significant stabilizing noncovalent interactions between the three phenyl groups, as evaluated both experimentally and theoretically. (Figure Presented).",

author = "Tatsuki Morimoto and Hidemitsu Uno and Hiroyuki Furuta",

year = "2007",

doi = "10.1002/anie.200604371",

language = "English",

volume = "46",

pages = "3672--3675",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "20",

}

TY - JOUR

T1 - Benzene ring trimer interactions modulate supramolecular structures

AU - Morimoto, Tatsuki

AU - Uno, Hidemitsu

AU - Furuta, Hiroyuki

PY - 2007

Y1 - 2007

N2 - Ring a ring of benzenes: An unsubstituted N-confused metalloporphyrin forms both C3- and C1-symmetric trimers in solution, whereas its monophenyl-substituted analogue forms exclusively C3-symmetric trimers (see picture) owing to significant stabilizing noncovalent interactions between the three phenyl groups, as evaluated both experimentally and theoretically. (Figure Presented).

AB - Ring a ring of benzenes: An unsubstituted N-confused metalloporphyrin forms both C3- and C1-symmetric trimers in solution, whereas its monophenyl-substituted analogue forms exclusively C3-symmetric trimers (see picture) owing to significant stabilizing noncovalent interactions between the three phenyl groups, as evaluated both experimentally and theoretically. (Figure Presented).

UR - http://www.scopus.com/inward/record.url?scp=34250803832&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250803832&partnerID=8YFLogxK

U2 - 10.1002/anie.200604371

DO - 10.1002/anie.200604371

M3 - Article

C2 - 17575557

AN - SCOPUS:34250803832

SN - 1433-7851

VL - 46

SP - 3672

EP - 3675

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 20

ER -

Benzene ring trimer interactions modulate supramolecular structures

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this