Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

Shogo Kuriyama; Kazuya Arashiba; Kazunari Nakajima; Hiromasa Tanaka; Kazunari Yoshizawa; Yoshiaki Nishibayashi

doi:10.1002/ejic.201601051

Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

Shogo Kuriyama
, Kazuya Arashiba
, Kazunari Nakajima
, Hiromasa Tanaka
, Kazunari Yoshizawa
, Yoshiaki Nishibayashi

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

A series of azaferrocene-based PNP-type pincer ligands were designed and prepared as new PNP-type pincer ligands. Some transition-metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene-based PNP-type pincer ligands were also prepared and characterized by X-ray analysis. The stoichiometric and catalytic reactivities of molybdenum–dinitrogen complexes toward nitrogen fixation were investigated in detail.

Original language	English
Pages (from-to)	4856-4861
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Volume	2016
Issue number	30
DOIs	https://doi.org/10.1002/ejic.201601051
Publication status	Published - Oct 2016

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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title = "Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation",

abstract = "A series of azaferrocene-based PNP-type pincer ligands were designed and prepared as new PNP-type pincer ligands. Some transition-metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene-based PNP-type pincer ligands were also prepared and characterized by X-ray analysis. The stoichiometric and catalytic reactivities of molybdenum–dinitrogen complexes toward nitrogen fixation were investigated in detail.",

author = "Shogo Kuriyama and Kazuya Arashiba and Kazunari Nakajima and Hiromasa Tanaka and Kazunari Yoshizawa and Yoshiaki Nishibayashi",

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T2 - Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

AU - Kuriyama, Shogo

AU - Arashiba, Kazuya

AU - Nakajima, Kazunari

AU - Tanaka, Hiromasa

AU - Yoshizawa, Kazunari

AU - Nishibayashi, Yoshiaki

PY - 2016/10

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AB - A series of azaferrocene-based PNP-type pincer ligands were designed and prepared as new PNP-type pincer ligands. Some transition-metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene-based PNP-type pincer ligands were also prepared and characterized by X-ray analysis. The stoichiometric and catalytic reactivities of molybdenum–dinitrogen complexes toward nitrogen fixation were investigated in detail.

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UR - https://www.scopus.com/pages/publications/84989288241#tab=citedBy

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DO - 10.1002/ejic.201601051

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 30

ER -

Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

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