Asymmetric synthesis of C2-symmetric 5,6-bis(benzyloxy)-cyclohexa-1,3-diene and a tricarbonyliron complex

Akiko Watanabe; Takao Kamahori; Mariko Aso; Hiroshi Suemune

doi:10.1039/b205526k

Asymmetric synthesis of C₂-symmetric 5,6-bis(benzyloxy)-cyclohexa-1,3-diene and a tricarbonyliron complex

Akiko Watanabe, Takao Kamahori, Mariko Aso, Hiroshi Suemune

Chemo-Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The C₂-symmetric 5,6-bis(benzyloxy)cyclohexa-1,3-diene and the corresponding tricarbonyliron complex have been synthesized in enantiomerically pure form. Reaction of the complex with trialkylaluminium gave a mono-alkylated product accompanied by racemization.

Original language	English
Pages (from-to)	2539-2543
Number of pages	5
Journal	Journal of the Chemical Society. Perkin Transactions 1
Volume	22
DOIs	https://doi.org/10.1039/b205526k
Publication status	Published - Jan 1 2002

All Science Journal Classification (ASJC) codes

Chemistry(all)

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abstract = "The C2-symmetric 5,6-bis(benzyloxy)cyclohexa-1,3-diene and the corresponding tricarbonyliron complex have been synthesized in enantiomerically pure form. Reaction of the complex with trialkylaluminium gave a mono-alkylated product accompanied by racemization.",

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AU - Suemune, Hiroshi

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AB - The C2-symmetric 5,6-bis(benzyloxy)cyclohexa-1,3-diene and the corresponding tricarbonyliron complex have been synthesized in enantiomerically pure form. Reaction of the complex with trialkylaluminium gave a mono-alkylated product accompanied by racemization.

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Asymmetric synthesis of C₂-symmetric 5,6-bis(benzyloxy)-cyclohexa-1,3-diene and a tricarbonyliron complex

Abstract

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