Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water

Yasuro Niidome; Takashi Kawazoe; Sunao Yamada

Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water

Yasuro Niidome, Takashi Kawazoe, Sunao Yamada

Research output: Contribution to journal › Conference article › peer-review

Abstract

One surface of a very thin poly(maleic anhydride-alt-1-octadecene)(PMAO) film was treated with an SHG-active dye (Disperse Orange3:DO3) on water. The DO3-treated PMAO film showed a clear second harmonic generation (SHG) response. It is suggested that the asymmetric incorporation is achieved by taking the form of -CO₂^-N⁺H₃-between the amino group of DO3 and the carboxyl group of PMAO formed by hydrolysis of maleic anhydride moiety. The results were compared with those in poly(methyl methacrylate) and poly(vinyl chloride) films having less and no SHG responses, respectively.

Original language	English
Pages (from-to)	119-122
Number of pages	4
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics
Volume	22
Issue number	1-4
Publication status	Published - Dec 1 1999
Event	Proceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference - Chitose, Jpn Duration: Oct 12 1998 → Oct 15 1998

All Science Journal Classification (ASJC) codes

Control and Systems Engineering
Condensed Matter Physics

Cite this

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title = "Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water",

abstract = "One surface of a very thin poly(maleic anhydride-alt-1-octadecene)(PMAO) film was treated with an SHG-active dye (Disperse Orange3:DO3) on water. The DO3-treated PMAO film showed a clear second harmonic generation (SHG) response. It is suggested that the asymmetric incorporation is achieved by taking the form of -CO2-N+H3-between the amino group of DO3 and the carboxyl group of PMAO formed by hydrolysis of maleic anhydride moiety. The results were compared with those in poly(methyl methacrylate) and poly(vinyl chloride) films having less and no SHG responses, respectively.",

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note = "Proceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference ; Conference date: 12-10-1998 Through 15-10-1998",

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TY - JOUR

T1 - Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water

AU - Niidome, Yasuro

AU - Kawazoe, Takashi

AU - Yamada, Sunao

PY - 1999/12/1

Y1 - 1999/12/1

N2 - One surface of a very thin poly(maleic anhydride-alt-1-octadecene)(PMAO) film was treated with an SHG-active dye (Disperse Orange3:DO3) on water. The DO3-treated PMAO film showed a clear second harmonic generation (SHG) response. It is suggested that the asymmetric incorporation is achieved by taking the form of -CO2-N+H3-between the amino group of DO3 and the carboxyl group of PMAO formed by hydrolysis of maleic anhydride moiety. The results were compared with those in poly(methyl methacrylate) and poly(vinyl chloride) films having less and no SHG responses, respectively.

AB - One surface of a very thin poly(maleic anhydride-alt-1-octadecene)(PMAO) film was treated with an SHG-active dye (Disperse Orange3:DO3) on water. The DO3-treated PMAO film showed a clear second harmonic generation (SHG) response. It is suggested that the asymmetric incorporation is achieved by taking the form of -CO2-N+H3-between the amino group of DO3 and the carboxyl group of PMAO formed by hydrolysis of maleic anhydride moiety. The results were compared with those in poly(methyl methacrylate) and poly(vinyl chloride) films having less and no SHG responses, respectively.

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M3 - Conference article

AN - SCOPUS:0033347728

SN - 1058-7268

VL - 22

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JO - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

JF - Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics

IS - 1-4

T2 - Proceedings of the 1998 4th International Conference on Organic Nonlinear Optics (ICONO'4) - The 8th IKETANI Conference

Y2 - 12 October 1998 through 15 October 1998

ER -

Asymmetric incorporation of an SHG-active dye at the surface of a thin polymer film on water

Abstract

All Science Journal Classification (ASJC) codes

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