Asymmetric epoxidation of conjugated olefins with dioxygen

Shota Koya; Yota Nishioka; Hirotaka Mizoguchi; Tatsuya Uchida; Tsutomu Katsuki

doi:10.1002/anie.201201848

Asymmetric epoxidation of conjugated olefins with dioxygen

Shota Koya, Yota Nishioka, Hirotaka Mizoguchi, Tatsuya Uchida, Tsutomu Katsuki

Division for Experimental Natural Science

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

A complex situation: Asymmetric epoxidation of conjugated olefins was achieved at room temperature using ruthenium complex 1 as the catalyst and air as the oxidant to give epoxides in up to 95 % ee (see scheme). When the product was acid sensitive, the reaction was carried out at 0 °C under oxygen.

Original language	English
Pages (from-to)	8243-8246
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	33
DOIs	https://doi.org/10.1002/anie.201201848
Publication status	Published - Aug 13 2012

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.201201848

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abstract = "A complex situation: Asymmetric epoxidation of conjugated olefins was achieved at room temperature using ruthenium complex 1 as the catalyst and air as the oxidant to give epoxides in up to 95 % ee (see scheme). When the product was acid sensitive, the reaction was carried out at 0 °C under oxygen.",

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AU - Nishioka, Yota

AU - Mizoguchi, Hirotaka

AU - Uchida, Tatsuya

AU - Katsuki, Tsutomu

PY - 2012/8/13

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Asymmetric epoxidation of conjugated olefins with dioxygen

Abstract

All Science Journal Classification (ASJC) codes

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