Application of room temperature ionic liquids to Li batteries

Hikari Sakaebe; Hajime Matsumoto; Kuniaki Tatsumi

doi:10.1016/j.electacta.2007.02.054

Application of room temperature ionic liquids to Li batteries

Hikari Sakaebe, Hajime Matsumoto, Kuniaki Tatsumi

Research output: Contribution to journal › Article › peer-review

220 Citations (Scopus)

Abstract

Novel electrolyte materials, room temperature ionic liquids (RTILs) were applied to the Li battery system and their characteristics in Li-metal batteries are discussed, partly reviewing authors work in the past. Quaternary ammonium (QA) cation-imide RTIL was focused on because of the excellent stability in cathodic environment of Li. Li/LiCoO₂ cell performance and Li cycling efficiency using the selected QA-imide RTIL was almost satisfactory. In addition, thermal stability of selected QA-imide RTIL with the charged positive electrode and Li was the advantage for Li battery. On the other hand, further improvement in the conducting properties is required with balanced approach for both electrochemical stability and thermal stability in order to use the RTIL electrolyte practically in batteries.

Original language	English
Pages (from-to)	1048-1054
Number of pages	7
Journal	Electrochimica Acta
Volume	53
Issue number	3 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.electacta.2007.02.054
Publication status	Published - Dec 20 2007
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemical Engineering(all)
Electrochemistry

Access to Document

10.1016/j.electacta.2007.02.054

Cite this

@article{24876efd945e4eb2b7f09ff84e3f8e26,

title = "Application of room temperature ionic liquids to Li batteries",

abstract = "Novel electrolyte materials, room temperature ionic liquids (RTILs) were applied to the Li battery system and their characteristics in Li-metal batteries are discussed, partly reviewing authors work in the past. Quaternary ammonium (QA) cation-imide RTIL was focused on because of the excellent stability in cathodic environment of Li. Li/LiCoO2 cell performance and Li cycling efficiency using the selected QA-imide RTIL was almost satisfactory. In addition, thermal stability of selected QA-imide RTIL with the charged positive electrode and Li was the advantage for Li battery. On the other hand, further improvement in the conducting properties is required with balanced approach for both electrochemical stability and thermal stability in order to use the RTIL electrolyte practically in batteries.",

author = "Hikari Sakaebe and Hajime Matsumoto and Kuniaki Tatsumi",

note = "Funding Information: Part of this study was supported in part by the project for the lithium battery by the New Energy and Industrial Technology Development Organization (NEDO) and Minister of Economy, Technology and Industry (METI) in Japan. ",

year = "2007",

month = dec,

day = "20",

doi = "10.1016/j.electacta.2007.02.054",

language = "English",

volume = "53",

pages = "1048--1054",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Limited",

number = "3 SPEC. ISS.",

}

TY - JOUR

T1 - Application of room temperature ionic liquids to Li batteries

AU - Sakaebe, Hikari

AU - Matsumoto, Hajime

AU - Tatsumi, Kuniaki

N1 - Funding Information: Part of this study was supported in part by the project for the lithium battery by the New Energy and Industrial Technology Development Organization (NEDO) and Minister of Economy, Technology and Industry (METI) in Japan.

PY - 2007/12/20

Y1 - 2007/12/20

N2 - Novel electrolyte materials, room temperature ionic liquids (RTILs) were applied to the Li battery system and their characteristics in Li-metal batteries are discussed, partly reviewing authors work in the past. Quaternary ammonium (QA) cation-imide RTIL was focused on because of the excellent stability in cathodic environment of Li. Li/LiCoO2 cell performance and Li cycling efficiency using the selected QA-imide RTIL was almost satisfactory. In addition, thermal stability of selected QA-imide RTIL with the charged positive electrode and Li was the advantage for Li battery. On the other hand, further improvement in the conducting properties is required with balanced approach for both electrochemical stability and thermal stability in order to use the RTIL electrolyte practically in batteries.

AB - Novel electrolyte materials, room temperature ionic liquids (RTILs) were applied to the Li battery system and their characteristics in Li-metal batteries are discussed, partly reviewing authors work in the past. Quaternary ammonium (QA) cation-imide RTIL was focused on because of the excellent stability in cathodic environment of Li. Li/LiCoO2 cell performance and Li cycling efficiency using the selected QA-imide RTIL was almost satisfactory. In addition, thermal stability of selected QA-imide RTIL with the charged positive electrode and Li was the advantage for Li battery. On the other hand, further improvement in the conducting properties is required with balanced approach for both electrochemical stability and thermal stability in order to use the RTIL electrolyte practically in batteries.

UR - http://www.scopus.com/inward/record.url?scp=35348944482&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=35348944482&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2007.02.054

DO - 10.1016/j.electacta.2007.02.054

M3 - Article

AN - SCOPUS:35348944482

SN - 0013-4686

VL - 53

SP - 1048

EP - 1054

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 3 SPEC. ISS.

ER -

Application of room temperature ionic liquids to Li batteries

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this