An excellent OER electrocatalyst of cubic SrCoO3-δ prepared by a simple F-doping strategy

Wanhua Wang, Yi Yang, Daoming Huan, Likun Wang, Nai Shi, Yun Xie, Changrong Xia, Ranran Peng, Yalin Lu

Research output: Contribution to journalArticlepeer-review

94 Citations (Scopus)


Driven by the increasing global energy demand, the development of innovative energy conversion and storage systems is becoming more and more urgent. As one of the attractive means, water splitting has attracted widespread attention because of its great potential in storing electricity in the form of chemical fuel which also makes it a promising solution to the utilization of non-grid electricity generated by solar or wind. The oxygen evolution reaction (OER) is generally deemed as the key rate-limiting step of water splitting, and thus studying efficient OER electrocatalysts with a low overpotential and good stability is of vital importance. Here, we successfully prepared an OER catalyst with excellent electrochemical performance through a simple anion doping. Firstly, a stable cubic perovskite SrCoO3-δ was prepared by anion F-doping instead of traditional A and/or B site doping. Secondly, SrCoO2.85-δF0.15 demonstrates excellent OER activity superior to its parent hexagonal compound H-Sr2Co2O5 and those perovskites prepared via complicated A- and/or B-site doping. DFT calculations and XPS investigations reveal that the cubic structure and the highly oxidative oxygen species (O22-/O-) via F- doping jointly contribute to the better OER properties of SrCoO2.85-δF0.15. Our work brings forth a promising strategy to stabilize cubic structures from hexagonal ones via a simple anion doping strategy, which may open a new avenue for the development of even more effective OER catalysts and may be applied in many other fields related to structure transformation, in addition to energy and catalysis fields.

Original languageEnglish
Pages (from-to)12538-12546
Number of pages9
JournalJournal of Materials Chemistry A
Issue number20
Publication statusPublished - 2019
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)


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