An acid-stable organoruthenium complex suitable as a bidentate building block

Chunbai Zheng; Daisuke Inoki; Takahiro Matsumoto; Seiji Ogo

doi:10.1246/cl.2010.130

An acid-stable organoruthenium complex suitable as a bidentate building block

Chunbai Zheng, Daisuke Inoki, Takahiro Matsumoto, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

Abstract

A new, water-soluble organoruthenium(II) sulfato complex [Ru _II(SO ₄)(Bz∧py)] {1, Bz∧py = 2-(pentamethylbenzyl)pyridine} has been synthesized and is stable at pH from 2.0 to 8.0. This complex has a bidentate sulfato ligand as a leaving group and is a good building block for "concerto catalysis": a new way of thinking in catalysis that bridges hetero- and homogeneous catalysis.

Original language	English
Pages (from-to)	130-131
Number of pages	2
Journal	Chemistry Letters
Volume	39
Issue number	2
DOIs	https://doi.org/10.1246/cl.2010.130
Publication status	Published - 2010

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2010.130

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abstract = "A new, water-soluble organoruthenium(II) sulfato complex [Ru II(SO 4)(Bz∧py)] {1, Bz∧py = 2-(pentamethylbenzyl)pyridine} has been synthesized and is stable at pH from 2.0 to 8.0. This complex has a bidentate sulfato ligand as a leaving group and is a good building block for {"}concerto catalysis{"}: a new way of thinking in catalysis that bridges hetero- and homogeneous catalysis.",

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PY - 2010

Y1 - 2010

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AB - A new, water-soluble organoruthenium(II) sulfato complex [Ru II(SO 4)(Bz∧py)] {1, Bz∧py = 2-(pentamethylbenzyl)pyridine} has been synthesized and is stable at pH from 2.0 to 8.0. This complex has a bidentate sulfato ligand as a leaving group and is a good building block for "concerto catalysis": a new way of thinking in catalysis that bridges hetero- and homogeneous catalysis.

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An acid-stable organoruthenium complex suitable as a bidentate building block

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