An abrupt spin transition based on short S⋯S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring

Kazuyuki Takahashi; Tomoko Kawakami; Zhong Ze Gu; Yasuaki Einaga; Akira Fujishima; Osamu Sato

doi:10.1039/b308070f

An abrupt spin transition based on short S⋯S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring

Kazuyuki Takahashi, Tomoko Kawakami, Zhong Ze Gu, Yasuaki Einaga, Akira Fujishima, Osamu Sato

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

The first preparation of an Fe(II) spin-crossover complex including a 1,3-dithiole ligand is reported. Crystal analyses of both the low- and the high-temperature phases reveal that short S⋯S contacts play a key role in an abrupt spin transition.

Original language	English
Pages (from-to)	2374-2375
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	18
DOIs	https://doi.org/10.1039/b308070f
Publication status	Published - 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b308070f

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title = "An abrupt spin transition based on short S⋯S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring",

abstract = "The first preparation of an Fe(II) spin-crossover complex including a 1,3-dithiole ligand is reported. Crystal analyses of both the low- and the high-temperature phases reveal that short S⋯S contacts play a key role in an abrupt spin transition.",

author = "Kazuyuki Takahashi and Tomoko Kawakami and Gu, {Zhong Ze} and Yasuaki Einaga and Akira Fujishima and Osamu Sato",

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AU - Takahashi, Kazuyuki

AU - Kawakami, Tomoko

AU - Gu, Zhong Ze

AU - Einaga, Yasuaki

AU - Fujishima, Akira

AU - Sato, Osamu

PY - 2003

Y1 - 2003

N2 - The first preparation of an Fe(II) spin-crossover complex including a 1,3-dithiole ligand is reported. Crystal analyses of both the low- and the high-temperature phases reveal that short S⋯S contacts play a key role in an abrupt spin transition.

AB - The first preparation of an Fe(II) spin-crossover complex including a 1,3-dithiole ligand is reported. Crystal analyses of both the low- and the high-temperature phases reveal that short S⋯S contacts play a key role in an abrupt spin transition.

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JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

An abrupt spin transition based on short S⋯S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring

Abstract

All Science Journal Classification (ASJC) codes

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