TY - JOUR
T1 - Aerobic C-H Oxidation of Arenes Using a Recyclable, Heterogeneous Rhodium Catalyst
AU - Matsumoto, Kenji
AU - Tachikawa, Shohei
AU - Hashimoto, Noriko
AU - Nakano, Rina
AU - Yoshida, Masahiro
AU - Shindo, Mitsuru
N1 - Publisher Copyright:
© 2017 American Chemical Society.
PY - 2017/4/21
Y1 - 2017/4/21
N2 - A novel, practical protocol for the aerobic direct C-H acetoxylation of arenes, employing a recyclable heterogeneous rhodium catalyst, is reported herein. The trifluoroacetoxylation of 2-amido-substituted anthracenes proceeded at the 9-position with exclusive regioselectivity. The oxidation of variously substituted anthracenes and other polycyclic aromatics with molecular oxygen as a terminal oxidant proceeded under mild conditions, providing products in good to excellent yields.
AB - A novel, practical protocol for the aerobic direct C-H acetoxylation of arenes, employing a recyclable heterogeneous rhodium catalyst, is reported herein. The trifluoroacetoxylation of 2-amido-substituted anthracenes proceeded at the 9-position with exclusive regioselectivity. The oxidation of variously substituted anthracenes and other polycyclic aromatics with molecular oxygen as a terminal oxidant proceeded under mild conditions, providing products in good to excellent yields.
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U2 - 10.1021/acs.joc.7b00300
DO - 10.1021/acs.joc.7b00300
M3 - Article
C2 - 28349687
AN - SCOPUS:85018484258
SN - 0022-3263
VL - 82
SP - 4305
EP - 4316
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 8
ER -