A Water-soluble Ni Dihydrido Complex That Reduces O2 to H2O in Water

Keisuke Takashita; Takahiro Matsumoto; Takeshi Yatabe; Hidetaka Nakai; Masatatsu Suzuki; Seiji Ogo

doi:10.1246/cl.150935

A Water-soluble Ni Dihydrido Complex That Reduces O₂ to H₂O in Water

Keisuke Takashita
, Takahiro Matsumoto
, Takeshi Yatabe
, Hidetaka Nakai
, Masatatsu Suzuki
, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

We report the first example of reduction of O₂ to H₂O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O₂ by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1HNMR, ESR, and UV-vis spectroscopies.

Original language	English
Pages (from-to)	72-74
Number of pages	3
Journal	Chemistry Letters
Volume	45
Issue number	1
DOIs	https://doi.org/10.1246/cl.150935
Publication status	Published - 2016

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1246/cl.150935

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abstract = "We report the first example of reduction of O2 to H2O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O2 by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1HNMR, ESR, and UV-vis spectroscopies.",

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AU - Takashita, Keisuke

AU - Matsumoto, Takahiro

AU - Yatabe, Takeshi

AU - Nakai, Hidetaka

AU - Suzuki, Masatatsu

AU - Ogo, Seiji

PY - 2016

Y1 - 2016

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AB - We report the first example of reduction of O2 to H2O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O2 by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1HNMR, ESR, and UV-vis spectroscopies.

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A Water-soluble Ni Dihydrido Complex That Reduces O₂ to H₂O in Water

Abstract

All Science Journal Classification (ASJC) codes

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