A Water-soluble Ni Dihydrido Complex That Reduces O2 to H2O in Water

Keisuke Takashita; Takahiro Matsumoto; Takeshi Yatabe; Hidetaka Nakai; Masatatsu Suzuki; Seiji Ogo

doi:10.1246/cl.150935

A Water-soluble Ni Dihydrido Complex That Reduces O₂ to H₂O in Water

Keisuke Takashita, Takahiro Matsumoto, Takeshi Yatabe, Hidetaka Nakai, Masatatsu Suzuki, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

We report the first example of reduction of O₂ to H₂O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O₂ by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1HNMR, ESR, and UV-vis spectroscopies.

Original language	English
Pages (from-to)	72-74
Number of pages	3
Journal	Chemistry Letters
Volume	45
Issue number	1
DOIs	https://doi.org/10.1246/cl.150935
Publication status	Published - 2016

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1246/cl.150935

Cite this

@article{cfda7ec69bda45c1a11d6afc890b12ea,

title = "A Water-soluble Ni Dihydrido Complex That Reduces O2 to H2O in Water",

abstract = "We report the first example of reduction of O2 to H2O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O2 by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1HNMR, ESR, and UV-vis spectroscopies.",

author = "Keisuke Takashita and Takahiro Matsumoto and Takeshi Yatabe and Hidetaka Nakai and Masatatsu Suzuki and Seiji Ogo",

note = "Publisher Copyright: {\textcopyright} 2016 The Chemical Society of Japan.",

year = "2016",

doi = "10.1246/cl.150935",

language = "English",

volume = "45",

pages = "72--74",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "1",

}

TY - JOUR

T1 - A Water-soluble Ni Dihydrido Complex That Reduces O2 to H2O in Water

AU - Takashita, Keisuke

AU - Matsumoto, Takahiro

AU - Yatabe, Takeshi

AU - Nakai, Hidetaka

AU - Suzuki, Masatatsu

AU - Ogo, Seiji

PY - 2016

Y1 - 2016

N2 - We report the first example of reduction of O2 to H2O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O2 by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1HNMR, ESR, and UV-vis spectroscopies.

AB - We report the first example of reduction of O2 to H2O by a Ni(II) dihydrido species. Isotope-labeling experiments reveal a four-electron reduction of O2 by the dihydrido species. The water-soluble Ni(II) dihydrido species was characterized by X-ray analysis, electrospray ionization mass spectrometry, and IR, 1HNMR, ESR, and UV-vis spectroscopies.

UR - http://www.scopus.com/inward/record.url?scp=84954113636&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84954113636&partnerID=8YFLogxK

U2 - 10.1246/cl.150935

DO - 10.1246/cl.150935

M3 - Article

AN - SCOPUS:84954113636

SN - 0366-7022

VL - 45

SP - 72

EP - 74

JO - Chemistry Letters

JF - Chemistry Letters

IS - 1

ER -

A Water-soluble Ni Dihydrido Complex That Reduces O₂ to H₂O in Water

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this