A water-soluble iridium(III) porphyrin

Hironobu Kanemitsu; Ryosuke Harada; Seiji Ogo

doi:10.1039/c000263a

A water-soluble iridium(III) porphyrin

Hironobu Kanemitsu, Ryosuke Harada, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

This work reports the synthesis and characterization of the first water-soluble iridium porphyrin, iridium(III) diaqua porphyrin [Ir ^III(TSPP)(OH₂)₂]^3- (1, TSPP = tetra-p-sulfonatophenyl porphyrin). The structure of 1 was unequivocally determined by single crystal X-ray analysis. Benzo-18-crown-6-ether is essential for producing single crystals suitable for X-ray analysis.

Original language	English
Pages (from-to)	3083-3085
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	18
DOIs	https://doi.org/10.1039/c000263a
Publication status	Published - 2010

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c000263a

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AU - Harada, Ryosuke

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AB - This work reports the synthesis and characterization of the first water-soluble iridium porphyrin, iridium(III) diaqua porphyrin [Ir III(TSPP)(OH2)2]3- (1, TSPP = tetra-p-sulfonatophenyl porphyrin). The structure of 1 was unequivocally determined by single crystal X-ray analysis. Benzo-18-crown-6-ether is essential for producing single crystals suitable for X-ray analysis.

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A water-soluble iridium(III) porphyrin

Abstract

All Science Journal Classification (ASJC) codes

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