A tetraruthenium carbonyl cluster bearing indenyl-type ligand as the facial bonding mode

Hideo Nagashima; Akihiro Suzuki; Hideo Kondo; Mitsuharu Nobata; Katsuyuki Aoki; Kenji Itoh

doi:10.1016/S0022-328X(98)01155-3

A tetraruthenium carbonyl cluster bearing indenyl-type ligand as the facial bonding mode

Hideo Nagashima, Akihiro Suzuki, Hideo Kondo, Mitsuharu Nobata, Katsuyuki Aoki, Kenji Itoh

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A tetraruthenium carbonyl cluster, (μ₃:η¹:η³:η ⁵-3,4,5-trihydroacenaphthylenyl)Ru₄H(CO)₉ (3), was synthesized from (μ₃:η¹:η ⁵-dihydroacenaphthylene)Ru₃H₂(CO)₁₂ (2) in chloroform. The molecular structure showed the trihydroacenaphthylenyl ligand to be a rare example of triply bridging nine electron donor ligands, being bound to three ruthenium atoms by the face-capping mode. One ruthenium atom was bonded by the π-cyclopentadienyl coordination mode, whereas the latter two were bound to four carbons in the six-membered ring by the η¹:η³-bonding mode.

Original language	English
Pages (from-to)	239-244
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	580
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(98)01155-3
Publication status	Published - May 31 1999

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(98)01155-3

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title = "A tetraruthenium carbonyl cluster bearing indenyl-type ligand as the facial bonding mode",

abstract = "A tetraruthenium carbonyl cluster, (μ3:η1:η3:η 5-3,4,5-trihydroacenaphthylenyl)Ru4H(CO)9 (3), was synthesized from (μ3:η1:η 5-dihydroacenaphthylene)Ru3H2(CO)12 (2) in chloroform. The molecular structure showed the trihydroacenaphthylenyl ligand to be a rare example of triply bridging nine electron donor ligands, being bound to three ruthenium atoms by the face-capping mode. One ruthenium atom was bonded by the π-cyclopentadienyl coordination mode, whereas the latter two were bound to four carbons in the six-membered ring by the η1:η3-bonding mode.",

author = "Hideo Nagashima and Akihiro Suzuki and Hideo Kondo and Mitsuharu Nobata and Katsuyuki Aoki and Kenji Itoh",

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T1 - A tetraruthenium carbonyl cluster bearing indenyl-type ligand as the facial bonding mode

AU - Nagashima, Hideo

AU - Suzuki, Akihiro

AU - Kondo, Hideo

AU - Nobata, Mitsuharu

AU - Aoki, Katsuyuki

AU - Itoh, Kenji

PY - 1999/5/31

Y1 - 1999/5/31

N2 - A tetraruthenium carbonyl cluster, (μ3:η1:η3:η 5-3,4,5-trihydroacenaphthylenyl)Ru4H(CO)9 (3), was synthesized from (μ3:η1:η 5-dihydroacenaphthylene)Ru3H2(CO)12 (2) in chloroform. The molecular structure showed the trihydroacenaphthylenyl ligand to be a rare example of triply bridging nine electron donor ligands, being bound to three ruthenium atoms by the face-capping mode. One ruthenium atom was bonded by the π-cyclopentadienyl coordination mode, whereas the latter two were bound to four carbons in the six-membered ring by the η1:η3-bonding mode.

AB - A tetraruthenium carbonyl cluster, (μ3:η1:η3:η 5-3,4,5-trihydroacenaphthylenyl)Ru4H(CO)9 (3), was synthesized from (μ3:η1:η 5-dihydroacenaphthylene)Ru3H2(CO)12 (2) in chloroform. The molecular structure showed the trihydroacenaphthylenyl ligand to be a rare example of triply bridging nine electron donor ligands, being bound to three ruthenium atoms by the face-capping mode. One ruthenium atom was bonded by the π-cyclopentadienyl coordination mode, whereas the latter two were bound to four carbons in the six-membered ring by the η1:η3-bonding mode.

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A tetraruthenium carbonyl cluster bearing indenyl-type ligand as the facial bonding mode

Abstract

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