A supramolecular thermocell consisting of ferrocenecarboxylate and β-cyclodextrin that has a negative Seebeck coefficient

Teppei Yamada; Xiaopeng Zou; Yimin Liang; Nobuo Kimizuka

doi:10.1038/s41428-018-0061-7

A supramolecular thermocell consisting of ferrocenecarboxylate and β-cyclodextrin that has a negative Seebeck coefficient

Teppei Yamada, Xiaopeng Zou, Yimin Liang, Nobuo Kimizuka

Applied Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A p-type supramolecular thermocell was constructed with a ferrocenecarboxylate/ferroceniumcarboxylate pair. The Seebeck coefficient of the cell was improved from −0.86 to −1.20 mV K⁻¹ by the addition of β-cyclodextrin. Isothermal titration calorimetry and a theoretical investigation demonstrated that the host–guest interaction increased the Seebeck coefficient.

Original language	English
Pages (from-to)	771-774
Number of pages	4
Journal	Polymer Journal
Volume	50
Issue number	8
DOIs	https://doi.org/10.1038/s41428-018-0061-7
Publication status	Published - Aug 1 2018

All Science Journal Classification (ASJC) codes

Polymers and Plastics
Materials Chemistry

Access to Document

10.1038/s41428-018-0061-7

Cite this

@article{6c93b06edb924d8ba993372e665e6dc7,

title = "A supramolecular thermocell consisting of ferrocenecarboxylate and β-cyclodextrin that has a negative Seebeck coefficient",

abstract = "A p-type supramolecular thermocell was constructed with a ferrocenecarboxylate/ferroceniumcarboxylate pair. The Seebeck coefficient of the cell was improved from −0.86 to −1.20 mV K−1 by the addition of β-cyclodextrin. Isothermal titration calorimetry and a theoretical investigation demonstrated that the host–guest interaction increased the Seebeck coefficient.",

author = "Teppei Yamada and Xiaopeng Zou and Yimin Liang and Nobuo Kimizuka",

note = "Funding Information: Acknowledgements: This work was supported by JSPS KAKENHI Grant Numbers JP25220805, JP16H06513 (Coordination Asymmetry), 26708007 and 26600026, and by JST PRESTO Grant Number JPMJPR141D, Japan. Publisher Copyright: {\textcopyright} 2018, The Society of Polymer Science, Japan.",

year = "2018",

month = aug,

day = "1",

doi = "10.1038/s41428-018-0061-7",

language = "English",

volume = "50",

pages = "771--774",

journal = "Polymer Journal",

issn = "0032-3896",

publisher = "Nature Publishing Group",

number = "8",

}

TY - JOUR

T1 - A supramolecular thermocell consisting of ferrocenecarboxylate and β-cyclodextrin that has a negative Seebeck coefficient

AU - Yamada, Teppei

AU - Zou, Xiaopeng

AU - Liang, Yimin

AU - Kimizuka, Nobuo

N1 - Funding Information: Acknowledgements: This work was supported by JSPS KAKENHI Grant Numbers JP25220805, JP16H06513 (Coordination Asymmetry), 26708007 and 26600026, and by JST PRESTO Grant Number JPMJPR141D, Japan. Publisher Copyright: © 2018, The Society of Polymer Science, Japan.

PY - 2018/8/1

Y1 - 2018/8/1

N2 - A p-type supramolecular thermocell was constructed with a ferrocenecarboxylate/ferroceniumcarboxylate pair. The Seebeck coefficient of the cell was improved from −0.86 to −1.20 mV K−1 by the addition of β-cyclodextrin. Isothermal titration calorimetry and a theoretical investigation demonstrated that the host–guest interaction increased the Seebeck coefficient.

AB - A p-type supramolecular thermocell was constructed with a ferrocenecarboxylate/ferroceniumcarboxylate pair. The Seebeck coefficient of the cell was improved from −0.86 to −1.20 mV K−1 by the addition of β-cyclodextrin. Isothermal titration calorimetry and a theoretical investigation demonstrated that the host–guest interaction increased the Seebeck coefficient.

UR - http://www.scopus.com/inward/record.url?scp=85046155992&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85046155992&partnerID=8YFLogxK

U2 - 10.1038/s41428-018-0061-7

DO - 10.1038/s41428-018-0061-7

M3 - Article

AN - SCOPUS:85046155992

SN - 0032-3896

VL - 50

SP - 771

EP - 774

JO - Polymer Journal

JF - Polymer Journal

IS - 8

ER -

A supramolecular thermocell consisting of ferrocenecarboxylate and β-cyclodextrin that has a negative Seebeck coefficient

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this