A stable radical species from facile oxygenation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

Taro Koide; Gengo Kashiwazaki; Masaaki Suzuki; Ko Furukawa; Min Chul Yoon; Sung Cho; Dongho Kim; Atsuhiro Osuka

doi:10.1002/anie.200804570

A stable radical species from facile oxygenation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

Taro Koide, Gengo Kashiwazaki, Masaaki Suzuki, Ko Furukawa, Min Chul Yoon, Sung Cho, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

76 Citations (Scopus)

Abstract

(Figure Presented) A stable radical: The title compound 1 has been synthesized as the first example of a meso-free variant and characterized as a strongly aromatic macrocycle with a spectacles-like planar conformation. The incorporation of free meso positions is promising for the exploration of novel structural and electronic properties.

Original language	English
Pages (from-to)	9661-9665
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	50
DOIs	https://doi.org/10.1002/anie.200804570
Publication status	Published - Dec 1 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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abstract = "(Figure Presented) A stable radical: The title compound 1 has been synthesized as the first example of a meso-free variant and characterized as a strongly aromatic macrocycle with a spectacles-like planar conformation. The incorporation of free meso positions is promising for the exploration of novel structural and electronic properties.",

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AU - Koide, Taro

AU - Kashiwazaki, Gengo

AU - Suzuki, Masaaki

AU - Furukawa, Ko

AU - Yoon, Min Chul

AU - Cho, Sung

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2008/12/1

Y1 - 2008/12/1

N2 - (Figure Presented) A stable radical: The title compound 1 has been synthesized as the first example of a meso-free variant and characterized as a strongly aromatic macrocycle with a spectacles-like planar conformation. The incorporation of free meso positions is promising for the exploration of novel structural and electronic properties.

AB - (Figure Presented) A stable radical: The title compound 1 has been synthesized as the first example of a meso-free variant and characterized as a strongly aromatic macrocycle with a spectacles-like planar conformation. The incorporation of free meso positions is promising for the exploration of novel structural and electronic properties.

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DO - 10.1002/anie.200804570

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JO - Angewandte Chemie - International Edition

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A stable radical species from facile oxygenation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

Abstract

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