A Stable Non-Kekulé singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

Taro Koide; Ko Furukawa; Hiroshi Shinokubo; Jae Yoon Shin; Kil Suk Kim; Dongho Kim; Atsuhiro Osuka

doi:10.1021/ja101040s

A Stable Non-Kekulé singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

Taro Koide, Ko Furukawa, Hiroshi Shinokubo, Jae Yoon Shin, Kil Suk Kim, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

73 Citations (Scopus)

Abstract

A meso, meso-diketohexaphyrin was isolated and characterized as a chemically stable non-Kekulé singlet biradicaloid. Two unpaired electrons are seemingly delocalized on two tripyrrolic units separated by C-O bonds. These results underscore the potential of expanded porphyrins to achieve unique electronic states.

Original language	English
Pages (from-to)	7246-7247
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	21
DOIs	https://doi.org/10.1021/ja101040s
Publication status	Published - Jun 2 2010
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja101040s

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abstract = "A meso, meso-diketohexaphyrin was isolated and characterized as a chemically stable non-Kekul{\'e} singlet biradicaloid. Two unpaired electrons are seemingly delocalized on two tripyrrolic units separated by C-O bonds. These results underscore the potential of expanded porphyrins to achieve unique electronic states.",

author = "Taro Koide and Ko Furukawa and Hiroshi Shinokubo and Shin, {Jae Yoon} and Kim, {Kil Suk} and Dongho Kim and Atsuhiro Osuka",

year = "2010",

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doi = "10.1021/ja101040s",

language = "English",

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AU - Koide, Taro

AU - Furukawa, Ko

AU - Shinokubo, Hiroshi

AU - Shin, Jae Yoon

AU - Kim, Kil Suk

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2010/6/2

Y1 - 2010/6/2

N2 - A meso, meso-diketohexaphyrin was isolated and characterized as a chemically stable non-Kekulé singlet biradicaloid. Two unpaired electrons are seemingly delocalized on two tripyrrolic units separated by C-O bonds. These results underscore the potential of expanded porphyrins to achieve unique electronic states.

AB - A meso, meso-diketohexaphyrin was isolated and characterized as a chemically stable non-Kekulé singlet biradicaloid. Two unpaired electrons are seemingly delocalized on two tripyrrolic units separated by C-O bonds. These results underscore the potential of expanded porphyrins to achieve unique electronic states.

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A Stable Non-Kekulé singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1)

Abstract

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