A spin-crossover cluster of iron(II) exhibiting a mixed-spin structure and synergy between spin transition and magnetic interaction

Da Yu Wu; Osamu Sato; Yasuaki Einaga; Chun Ying Duan

doi:10.1002/anie.200804529

A spin-crossover cluster of iron(II) exhibiting a mixed-spin structure and synergy between spin transition and magnetic interaction

Da Yu Wu, Osamu Sato, Yasuaki Einaga, Chun Ying Duan

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

172 Citations (Scopus)

Abstract

How low can you go? An Fe^ll₄ square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centres. The spin-crossover sites are located on the same side of the square, and the spin transition and magnetic interactions (see picture) are synergistically coupled.

Original language	English
Pages (from-to)	1475-1478
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	8
DOIs	https://doi.org/10.1002/anie.200804529
Publication status	Published - Feb 9 2009

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.200804529

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AU - Duan, Chun Ying

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A spin-crossover cluster of iron(II) exhibiting a mixed-spin structure and synergy between spin transition and magnetic interaction

Abstract

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