A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: Spontaneous resolution and photoresponsive properties

Wen Zhang; Hao Ling Sun; Osamu Sato

doi:10.1039/c0ce00178c

A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: Spontaneous resolution and photoresponsive properties

Wen Zhang, Hao Ling Sun, Osamu Sato

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

A one-dimensional homochiral Mo^IVCu^II compound, [Cu(tren)][Cu(33)][Mo(CN)₈]·4H₂O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P2₁. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.

Original language	English
Pages (from-to)	4045-4047
Number of pages	3
Journal	CrystEngComm
Volume	12
Issue number	12
DOIs	https://doi.org/10.1039/c0ce00178c
Publication status	Published - Dec 2010

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1039/c0ce00178c

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abstract = "A one-dimensional homochiral MoIVCuII compound, [Cu(tren)][Cu(33)][Mo(CN)8]·4H2O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P21. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.",

author = "Wen Zhang and Sun, {Hao Ling} and Osamu Sato",

year = "2010",

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doi = "10.1039/c0ce00178c",

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AU - Sun, Hao Ling

AU - Sato, Osamu

PY - 2010/12

Y1 - 2010/12

N2 - A one-dimensional homochiral MoIVCuII compound, [Cu(tren)][Cu(33)][Mo(CN)8]·4H2O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P21. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.

AB - A one-dimensional homochiral MoIVCuII compound, [Cu(tren)][Cu(33)][Mo(CN)8]·4H2O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P21. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.

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A one-dimensional homochiral Mo(iv)-Cu(ii) coordination polymer: Spontaneous resolution and photoresponsive properties

Abstract

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