A novel UV-curing flame retardant film with significantly intumescent effect

Panyue Wen, Xiaofeng Wang, Xiaming Feng, Keqing Zhou, Bin Yu, Qiangjun Zhang, Qilong Tai, Lei Song, Yuan Hu, Richard K.K. Yuen

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

Abstract High flammability has always been a major challenge hindering in application of most conventional UV-curable resins. Herein, several intumescent flame-retardant (FR) films characterized with crosslinked network structure were successfully prepared via the combination of tri(acryloyloxyethyl) phosphate (TAEP) with melamine-based acrylate resin (MAAR) by UV-cured method. As compared with sole TAEP- or MAAR-containing films, the mixed films containing TAEP and MAAR exhibited improved flame retardant property. The characterizations of their flammability and char morphologies indicated that the PN-2 with 2/1 mass ratio of TAEP to MAAR had the relatively better flame retardance and could form the intumescent char layer with many thin-walled large bubbles under the compact surface layer. Furthermore, the evolved products for PN-2 with 2/1 mass ratio of TAEP to MAAR during the thermal degradation exhibited much less release than neat TAEP- or MAAR-containing coatings, which implied the increase of the pyrolysis products inside the char layer and thus leaded to the expansion of the intumescent FR films. These results suggest the UV-curing intumescent FR films containing TAEP and MAAR with appropriate ratio possess great flame retardant efficiency that in favor of further application on a substrate, such as fabrics, wood, and plastics.

Original languageEnglish
Article number7659
Pages (from-to)288-294
Number of pages7
JournalPolymer Degradation and Stability
Volume119
DOIs
Publication statusPublished - Jun 15 2015
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Mechanics of Materials
  • Polymers and Plastics
  • Materials Chemistry

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