A (Ni-SIr)I model for [NiFe]hydrogenase

Takahiro Matsumoto, Tatsuya Ando, Yuki Mori, Takeshi Yatabe, Hidetaka Nakai, Seiji Ogo

    Research output: Contribution to journalArticlepeer-review

    10 Citations (Scopus)

    Abstract

    We report the synthesis and characterization of a μ-hydroxo NiRu complex as a model for the active site of (Ni-SIr)I of [NiFe]hydrogenase. This is the first example of the (Ni-SIr)I model with a bridging hydroxo ligand between dimetal centers and an available coordination site on Ni center cis to the bridging hydroxo ligand. We have determined the structure of the (Ni-SIr)I model complex by X-ray analysis and reported reversible switching between the catalytically inactive (Ni-SIr)I and a catalytically active (Ni-SIr)II models.

    Original languageEnglish
    Pages (from-to)73-76
    Number of pages4
    JournalJournal of Organometallic Chemistry
    Volume796
    DOIs
    Publication statusPublished - Nov 1 2015

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Physical and Theoretical Chemistry
    • Organic Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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