A neutral five-coordinated organoruthenium(0) complex: X-ray structure and unique solvatochromism

Kihun Jeong; Harutaka Nakamori; Shunsuke Imai; Takahiro Matsumoto; Seiji Ogo; Hidetaka Nakai

doi:10.1246/cl.2012.650

A neutral five-coordinated organoruthenium(0) complex: X-ray structure and unique solvatochromism

Kihun Jeong, Harutaka Nakamori, Shunsuke Imai, Takahiro Matsumoto, Seiji Ogo, Hidetaka Nakai

Research output: Contribution to journal › Review article › peer-review

2 Citations (Scopus)

Abstract

The structure of a neutral five-coordinated organoruthenium( 0) complex [(η ⁶-C ₆Me ₆)Ru ⁰(bpy)] (1, bpy: 2,2′-bipyridine) was determined by X-ray diffraction analysis. The solvent-induced reversible color change based on the interconversion between the purple Ru ⁰ complex 1 and a yellow Ru ^IIhydride complex [(η ⁶-C ₆Me ₆)Ru ^II(bpy)H] ⁺ is presented.

Original language	English
Pages (from-to)	650-651
Number of pages	2
Journal	Chemistry Letters
Volume	41
Issue number	6
DOIs	https://doi.org/10.1246/cl.2012.650
Publication status	Published - 2012

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2012.650

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title = "A neutral five-coordinated organoruthenium(0) complex: X-ray structure and unique solvatochromism",

abstract = "The structure of a neutral five-coordinated organoruthenium( 0) complex [(η 6-C 6Me 6)Ru 0(bpy)] (1, bpy: 2,2′-bipyridine) was determined by X-ray diffraction analysis. The solvent-induced reversible color change based on the interconversion between the purple Ru 0 complex 1 and a yellow Ru IIhydride complex [(η 6-C 6Me 6)Ru II(bpy)H] + is presented.",

author = "Kihun Jeong and Harutaka Nakamori and Shunsuke Imai and Takahiro Matsumoto and Seiji Ogo and Hidetaka Nakai",

year = "2012",

doi = "10.1246/cl.2012.650",

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volume = "41",

pages = "650--651",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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T1 - A neutral five-coordinated organoruthenium(0) complex

T2 - X-ray structure and unique solvatochromism

AU - Jeong, Kihun

AU - Nakamori, Harutaka

AU - Imai, Shunsuke

AU - Matsumoto, Takahiro

AU - Ogo, Seiji

AU - Nakai, Hidetaka

PY - 2012

Y1 - 2012

N2 - The structure of a neutral five-coordinated organoruthenium( 0) complex [(η 6-C 6Me 6)Ru 0(bpy)] (1, bpy: 2,2′-bipyridine) was determined by X-ray diffraction analysis. The solvent-induced reversible color change based on the interconversion between the purple Ru 0 complex 1 and a yellow Ru IIhydride complex [(η 6-C 6Me 6)Ru II(bpy)H] + is presented.

AB - The structure of a neutral five-coordinated organoruthenium( 0) complex [(η 6-C 6Me 6)Ru 0(bpy)] (1, bpy: 2,2′-bipyridine) was determined by X-ray diffraction analysis. The solvent-induced reversible color change based on the interconversion between the purple Ru 0 complex 1 and a yellow Ru IIhydride complex [(η 6-C 6Me 6)Ru II(bpy)H] + is presented.

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U2 - 10.1246/cl.2012.650

DO - 10.1246/cl.2012.650

M3 - Review article

AN - SCOPUS:84861748593

SN - 0366-7022

VL - 41

SP - 650

EP - 651

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

A neutral five-coordinated organoruthenium(0) complex: X-ray structure and unique solvatochromism

Abstract

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