A naphthyl-substituted pentamethylcyclopentadienyl ligand and its Sm(ii) bent-metallocene complexes with solvent-induced structure change

Takeshi Yatabe; Masaki Karasawa; Kiyoshi Isobe; Seiji Ogo; Hidetaka Nakai

doi:10.1039/c1dt11844g

A naphthyl-substituted pentamethylcyclopentadienyl ligand and its Sm(ii) bent-metallocene complexes with solvent-induced structure change

Takeshi Yatabe, Masaki Karasawa, Kiyoshi Isobe, Seiji Ogo, Hidetaka Nakai

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A naphthyl-substituted pentamethylcyclopentadienyl ligand (Cp ^Naph = η ⁵-C ₅Me ₄CH ₂C ₁₀H ₇) and its Sm(ii) complexes [Sm(Cp ^Naph) ₂(THF) _x] (1: x = 2, 2: x = 0) have been prepared and characterised. The solvent-induced reversible conversion between the di-THF solvated purple complex 1 and the un-solvated dark green complex 2 is presented.

Original language	English
Pages (from-to)	354-356
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	2
DOIs	https://doi.org/10.1039/c1dt11844g
Publication status	Published - Jan 14 2012

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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AU - Yatabe, Takeshi

AU - Karasawa, Masaki

AU - Isobe, Kiyoshi

AU - Ogo, Seiji

AU - Nakai, Hidetaka

PY - 2012/1/14

Y1 - 2012/1/14

N2 - A naphthyl-substituted pentamethylcyclopentadienyl ligand (Cp Naph = η 5-C 5Me 4CH 2C 10H 7) and its Sm(ii) complexes [Sm(Cp Naph) 2(THF) x] (1: x = 2, 2: x = 0) have been prepared and characterised. The solvent-induced reversible conversion between the di-THF solvated purple complex 1 and the un-solvated dark green complex 2 is presented.

AB - A naphthyl-substituted pentamethylcyclopentadienyl ligand (Cp Naph = η 5-C 5Me 4CH 2C 10H 7) and its Sm(ii) complexes [Sm(Cp Naph) 2(THF) x] (1: x = 2, 2: x = 0) have been prepared and characterised. The solvent-induced reversible conversion between the di-THF solvated purple complex 1 and the un-solvated dark green complex 2 is presented.

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A naphthyl-substituted pentamethylcyclopentadienyl ligand and its Sm(ii) bent-metallocene complexes with solvent-induced structure change

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