A mer-Triaqua Rh complex with a terpyridine ligand

Daisuke Inoki; Takahiro Matsumoto; Hidetaka Nakai; Seiji Ogo

doi:10.1246/cl.2012.116

A mer-Triaqua Rh complex with a terpyridine ligand

Daisuke Inoki, Takahiro Matsumoto, Hidetaka Nakai, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

We report the synthesis of a mer-triaqua Rh ^III complex using terpyridine as a meridional tridentate ligand. This is the first example of a structurally characterized six-coordinated mertriaqua complex for any second- or third-row element from the main transition-metal groups (groups 511). This is also the first example of a structurally characterized mer-triaqua complex with terpyridine for any transition metal. Acid dissociation constants, pK _a1 and pK _a2, of the triaqua complex are determined to be 3.0 and 6.9, respectively.

Original language	English
Pages (from-to)	116-118
Number of pages	3
Journal	Chemistry Letters
Volume	41
Issue number	1
DOIs	https://doi.org/10.1246/cl.2012.116
Publication status	Published - 2012

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1246/cl.2012.116

Cite this

@article{76d703c2dff54e0c8c6471542d13d4d7,

title = "A mer-Triaqua Rh complex with a terpyridine ligand",

abstract = "We report the synthesis of a mer-triaqua Rh III complex using terpyridine as a meridional tridentate ligand. This is the first example of a structurally characterized six-coordinated mertriaqua complex for any second- or third-row element from the main transition-metal groups (groups 511). This is also the first example of a structurally characterized mer-triaqua complex with terpyridine for any transition metal. Acid dissociation constants, pK a1 and pK a2, of the triaqua complex are determined to be 3.0 and 6.9, respectively.",

author = "Daisuke Inoki and Takahiro Matsumoto and Hidetaka Nakai and Seiji Ogo",

year = "2012",

doi = "10.1246/cl.2012.116",

language = "English",

volume = "41",

pages = "116--118",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "1",

}

TY - JOUR

T1 - A mer-Triaqua Rh complex with a terpyridine ligand

AU - Inoki, Daisuke

AU - Matsumoto, Takahiro

AU - Nakai, Hidetaka

AU - Ogo, Seiji

PY - 2012

Y1 - 2012

N2 - We report the synthesis of a mer-triaqua Rh III complex using terpyridine as a meridional tridentate ligand. This is the first example of a structurally characterized six-coordinated mertriaqua complex for any second- or third-row element from the main transition-metal groups (groups 511). This is also the first example of a structurally characterized mer-triaqua complex with terpyridine for any transition metal. Acid dissociation constants, pK a1 and pK a2, of the triaqua complex are determined to be 3.0 and 6.9, respectively.

AB - We report the synthesis of a mer-triaqua Rh III complex using terpyridine as a meridional tridentate ligand. This is the first example of a structurally characterized six-coordinated mertriaqua complex for any second- or third-row element from the main transition-metal groups (groups 511). This is also the first example of a structurally characterized mer-triaqua complex with terpyridine for any transition metal. Acid dissociation constants, pK a1 and pK a2, of the triaqua complex are determined to be 3.0 and 6.9, respectively.

UR - http://www.scopus.com/inward/record.url?scp=84855304490&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84855304490&partnerID=8YFLogxK

U2 - 10.1246/cl.2012.116

DO - 10.1246/cl.2012.116

M3 - Article

AN - SCOPUS:84855304490

SN - 0366-7022

VL - 41

SP - 116

EP - 118

JO - Chemistry Letters

JF - Chemistry Letters

IS - 1

ER -

A mer-Triaqua Rh complex with a terpyridine ligand

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this