A heterometallic protocol for turn-on fluorescence. synthesis, structure and luminescence behavior of a diruthenium(III)magnesium(II) complex decorated with four pyrenecarboxylates

Atsushi Ikegami; Masaaki Abe; Yoshio Hisaeda

doi:10.1246/cl.131093

A heterometallic protocol for turn-on fluorescence. synthesis, structure and luminescence behavior of a diruthenium(III)magnesium(II) complex decorated with four pyrenecarboxylates

Atsushi Ikegami, Masaaki Abe, Yoshio Hisaeda

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2 Citations (Scopus)

Abstract

A new heterometallic diruthenium(III)magnesium(II) complex functionalized with four pyrenecarboxylate fluorophores 1 has been synthesized and structurally characterized. Fluorescence from the pyrene moieties in 1 was nearly completely quenched in CH₂ Cl₂ (>98%), but turn-on fluorescence was successfully observed after regioselective substitution of the carboxylates bridging the heterometallic Ru(III)..Mg(II) sites.

Original language	English
Pages (from-to)	456-458
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	4
DOIs	https://doi.org/10.1246/cl.131093
Publication status	Published - 2014

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.131093

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title = "A heterometallic protocol for turn-on fluorescence. synthesis, structure and luminescence behavior of a diruthenium(III)magnesium(II) complex decorated with four pyrenecarboxylates",

abstract = "A new heterometallic diruthenium(III)magnesium(II) complex functionalized with four pyrenecarboxylate fluorophores 1 has been synthesized and structurally characterized. Fluorescence from the pyrene moieties in 1 was nearly completely quenched in CH2 Cl2 (>98%), but turn-on fluorescence was successfully observed after regioselective substitution of the carboxylates bridging the heterometallic Ru(III)..Mg(II) sites.",

author = "Atsushi Ikegami and Masaaki Abe and Yoshio Hisaeda",

year = "2014",

doi = "10.1246/cl.131093",

language = "English",

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pages = "456--458",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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T1 - A heterometallic protocol for turn-on fluorescence. synthesis, structure and luminescence behavior of a diruthenium(III)magnesium(II) complex decorated with four pyrenecarboxylates

AU - Ikegami, Atsushi

AU - Abe, Masaaki

AU - Hisaeda, Yoshio

PY - 2014

Y1 - 2014

N2 - A new heterometallic diruthenium(III)magnesium(II) complex functionalized with four pyrenecarboxylate fluorophores 1 has been synthesized and structurally characterized. Fluorescence from the pyrene moieties in 1 was nearly completely quenched in CH2 Cl2 (>98%), but turn-on fluorescence was successfully observed after regioselective substitution of the carboxylates bridging the heterometallic Ru(III)..Mg(II) sites.

AB - A new heterometallic diruthenium(III)magnesium(II) complex functionalized with four pyrenecarboxylate fluorophores 1 has been synthesized and structurally characterized. Fluorescence from the pyrene moieties in 1 was nearly completely quenched in CH2 Cl2 (>98%), but turn-on fluorescence was successfully observed after regioselective substitution of the carboxylates bridging the heterometallic Ru(III)..Mg(II) sites.

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DO - 10.1246/cl.131093

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JF - Chemistry Letters

IS - 4

ER -

A heterometallic protocol for turn-on fluorescence. synthesis, structure and luminescence behavior of a diruthenium(III)magnesium(II) complex decorated with four pyrenecarboxylates

Abstract

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