A family of molecular nickel hydrogen evolution catalysts providing tunable overpotentials using ligand-centered proton-coupled electron transfer paths

Yutaro Aimoto; Keita Koshiba; Kosei Yamauchi; Ken Sakai

doi:10.1039/C8CC07467D

A family of molecular nickel hydrogen evolution catalysts providing tunable overpotentials using ligand-centered proton-coupled electron transfer paths

Yutaro Aimoto, Keita Koshiba, Kosei Yamauchi, Ken Sakai

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Two new nickel dithiolate derivatives have been examined for their electrocatalytic activity for the hydrogen evolution reaction (HER) in attempts to clarify whether the overpotential for the HER can be tuned upon varying the ligand-centered reduction potential that triggers the HER by the catalysts. We demonstrate the validity of this approach to achieve desirable tunability in the overpotential for the HER.

Original language	English
Pages (from-to)	12820-12823
Number of pages	3
Journal	Chemical Communications
Volume	91
DOIs	https://doi.org/10.1039/C8CC07467D
Publication status	Published - Oct 20 2018

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title = "A family of molecular nickel hydrogen evolution catalysts providing tunable overpotentials using ligand-centered proton-coupled electron transfer paths",

abstract = "Two new nickel dithiolate derivatives have been examined for their electrocatalytic activity for the hydrogen evolution reaction (HER) in attempts to clarify whether the overpotential for the HER can be tuned upon varying the ligand-centered reduction potential that triggers the HER by the catalysts. We demonstrate the validity of this approach to achieve desirable tunability in the overpotential for the HER.",

author = "Yutaro Aimoto and Keita Koshiba and Kosei Yamauchi and Ken Sakai",

year = "2018",

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doi = "10.1039/C8CC07467D",

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T1 - A family of molecular nickel hydrogen evolution catalysts providing tunable overpotentials using ligand-centered proton-coupled electron transfer paths

AU - Aimoto, Yutaro

AU - Koshiba, Keita

AU - Yamauchi, Kosei

AU - Sakai, Ken

PY - 2018/10/20

Y1 - 2018/10/20

N2 - Two new nickel dithiolate derivatives have been examined for their electrocatalytic activity for the hydrogen evolution reaction (HER) in attempts to clarify whether the overpotential for the HER can be tuned upon varying the ligand-centered reduction potential that triggers the HER by the catalysts. We demonstrate the validity of this approach to achieve desirable tunability in the overpotential for the HER.

AB - Two new nickel dithiolate derivatives have been examined for their electrocatalytic activity for the hydrogen evolution reaction (HER) in attempts to clarify whether the overpotential for the HER can be tuned upon varying the ligand-centered reduction potential that triggers the HER by the catalysts. We demonstrate the validity of this approach to achieve desirable tunability in the overpotential for the HER.

U2 - 10.1039/C8CC07467D

DO - 10.1039/C8CC07467D

M3 - Article

SN - 1359-7345

VL - 91

SP - 12820

EP - 12823

JO - Chemical Communications

JF - Chemical Communications

ER -

A family of molecular nickel hydrogen evolution catalysts providing tunable overpotentials using ligand-centered proton-coupled electron transfer paths

Abstract

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